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Palladium-catalyzed synthesis of N-vinyl pyrroles and indoles.

ABSTRACT: A stereospecific palladium-catalyzed N-vinylation of azaheterocycles with vinyl triflates is described. Cyclic and acyclic vinyl triflates along with nonnucleophilic azaheterocycles were found to be substrates for this palladium-catalyzed synthesis of N-vinyl pyrrole and indole derivatives.

SUBMITTER: Movassaghi M 

PROVIDER: S-EPMC5548004 | biostudies-literature | 2005 Oct

REPOSITORIES: biostudies-literature

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Palladium-catalyzed synthesis of N-vinyl pyrroles and indoles.

Movassaghi Mohammad M   Ondrus Alison E AE  

The Journal of organic chemistry 20051001 21

A stereospecific palladium-catalyzed N-vinylation of azaheterocycles with vinyl triflates is described. Cyclic and acyclic vinyl triflates along with nonnucleophilic azaheterocycles were found to be substrates for this palladium-catalyzed synthesis of N-vinyl pyrrole and indole derivatives. ...[more]

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