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Simulated photoelectron intensities at the aqueous solution-air interface for flat and cylindrical (microjet) geometries.


ABSTRACT: Ion spatial distributions at the aqueous-air/vacuum interface are accessible by energy-dependent X-ray photoelectron spectroscopy (XPS). Here we quantify the difference between a flat surface and a cylindrical microjet in terms of the energy-dependent information depth of the XPS experiment and in terms of the simulated photoelectron intensities using solutions of pure water and of 1 mol L-1 NaI as examples.

SUBMITTER: Olivieri G 

PROVIDER: S-EPMC5559733 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Simulated photoelectron intensities at the aqueous solution-air interface for flat and cylindrical (microjet) geometries.

Olivieri Giorgia G   Parry Krista M KM   Powell Cedric J CJ   Tobias Douglas J DJ   Brown Matthew A MA  

Physical chemistry chemical physics : PCCP 20170301 9


Ion spatial distributions at the aqueous-air/vacuum interface are accessible by energy-dependent X-ray photoelectron spectroscopy (XPS). Here we quantify the difference between a flat surface and a cylindrical microjet in terms of the energy-dependent information depth of the XPS experiment and in terms of the simulated photoelectron intensities using solutions of pure water and of 1 mol L<sup>-1</sup> NaI as examples. ...[more]

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