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Tactical tuning of the surface and interfacial properties of graphene: A Versatile and rational electrochemical approach.

ABSTRACT: Designing a versatile and rational method for the tactical tuning of the surface and interfacial properties of graphene is an essential yet challenging task of many scientific areas including health care, sensors, energy, and the environment. A method was designed herein to tackle the challenge and tune the surface and interfacial properties of graphene using a simple electrochemical tethering of arylamines that provides diverse reactive end groups to graphene. This method resulted in the preparation of graphenes with thiol, hydroxy, amine, carboxyl, and sulfonate surface functionalities respectively. X-ray photoelectron spectroscopy, scanning electron microscopy, and cyclic voltammetry were used to study the chemical, morphological, and electrochemical properties of the modified graphenes. The results show the promising scope of the reported method towards the tactical tuning of the surface and interfacial properties of graphene. Also, this method can give fundamental insights of the surface tuning of graphene and its structurally similar materials. Hence, this approach can be used to advantageously tune the surface properties of the other structurally similar nanocarbons and their hybrid materials to make them potential candidates for many applications.

SUBMITTER: Vusa CSR

PROVIDER: S-EPMC5567138 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature

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Tactical tuning of the surface and interfacial properties of graphene: A Versatile and rational electrochemical approach.

Vusa Chiranjeevi Srinivasa Rao CSR Venkatesan Manju M K Aneesh A Berchmans Sheela S Arumugam Palaniappan P

Scientific reports 20170821 1

Designing a versatile and rational method for the tactical tuning of the surface and interfacial properties of graphene is an essential yet challenging task of many scientific areas including health care, sensors, energy, and the environment. A method was designed herein to tackle the challenge and tune the surface and interfacial properties of graphene using a simple electrochemical tethering of arylamines that provides diverse reactive end groups to graphene. This method resulted in the prepar ...[more]

PMID: 28827778

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Project description:Surface chemical composition is fundamental to determining properties on the nanoscale, making precise control over surface chemistry critical to being able to optimise nanomaterials for virtually any application. Surface-engineering independent of the preparation of the underlying nanomaterial is particularly attractive for efficient, divergent synthetic strategies, and for the potential to create reactive, responsive and smart nanodevices. For monolayer-stabilised nanoparticles, established methods include ligand exchange to replace the ligand shell in its entirety, encapsulation with amphiphilic (macro)molecules, noncovalent interactions with surface-bound biomolecules, or a relatively limited number of covalent bond forming reactions. Yet, each of these approaches has considerable drawbacks. Here we show that dynamic covalent exchange at the periphery of the nanoparticle-stabilizing monolayer allows surface-bound ligand molecular structure to be substantially modified in mild and reversible processes that are independent of the nanoparticle-molecule interface. Simple stoichiometric variation allows the extent of exchange to be controlled, generating a range of kinetically stable mixed-monolayer compositions across an otherwise identical, self-consistent series of nanoparticles. This approach can be used to modulate nanoparticle properties that are defined by the monolayer composition. We demonstrate switching of nanoparticle solvent compatibility between widely differing solvents - spanning hexane to water - and the ability to tune solubility across the entire continuum between these extremes, all from a single nanoparticle starting point. We also demonstrate that fine control over mixed-monolayer composition influences the assembly of discrete, colloidally stable nanoparticle clusters. By carefully assessing monolayer composition in each state, using both in situ and ex situ methods, we are able to correlate the molecular-level details of the nanoparticle-bound monolayer with system-level properties and behaviour. These empirically determined relationships contribute fundamental insights on nanoscale structure-function relationships, which are currently beyond the capabilities of ab initio prediction.

Dataset Information

Tactical tuning of the surface and interfacial properties of graphene: A Versatile and rational electrochemical approach.

Publications

Tactical tuning of the surface and interfacial properties of graphene: A Versatile and rational electrochemical approach.

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