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Oriented Two-Dimensional Porous Organic Cage Crystals.

ABSTRACT: The formation of two-dimensional (2D) oriented porous organic cage crystals (consisting of imine-based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution-processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution-processable molecular crystalline 2D membranes for molecular separations.

SUBMITTER: Jiang S

PROVIDER: S-EPMC5577517 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature

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Oriented Two-Dimensional Porous Organic Cage Crystals.

Jiang Shan S Song Qilei Q Massey Alan A Chong Samantha Y SY Chen Linjiang L Sun Shijing S Hasell Tom T Raval Rasmita R Sivaniah Easan E Cheetham Anthony K AK Cooper Andrew I AI

Angewandte Chemie (International ed. in English) 20170706 32

The formation of two-dimensional (2D) oriented porous organic cage crystals (consisting of imine-based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution-processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated wi ...[more]

PMID: 28580700

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