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Core-Shell Crystals of Porous Organic Cages.

ABSTRACT: The first examples of core-shell porous molecular crystals are described. The physical properties of the core-shell crystals, such as surface hydrophobicity, CO2 ?/CH4 selectivity, are controlled by the chemical composition of the shell. This shows that porous core-shell molecular crystals can exhibit synergistic properties that out-perform materials built from the individual, constituent molecules.

SUBMITTER: Jiang S 

PROVIDER: S-EPMC6120484 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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Core-Shell Crystals of Porous Organic Cages.

Jiang Shan S   Du Yi Y   Marcello Marco M   Corcoran Edward W EW   Calabro David C DC   Chong Samantha Y SY   Chen Linjiang L   Clowes Rob R   Hasell Tom T   Cooper Andrew I AI  

Angewandte Chemie (International ed. in English) 20180610 35

The first examples of core-shell porous molecular crystals are described. The physical properties of the core-shell crystals, such as surface hydrophobicity, CO<sub>2</sub>  /CH<sub>4</sub> selectivity, are controlled by the chemical composition of the shell. This shows that porous core-shell molecular crystals can exhibit synergistic properties that out-perform materials built from the individual, constituent molecules. ...[more]

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