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The introduction of the Barbier reaction into polymer chemistry.

ABSTRACT: The Barbier reaction, a widely utilized reaction for carbon-carbon bond formation, has played important roles in modern organic chemistry for more than a century. Here, we show its successful introduction to polymer chemistry. Through one-pot Barbier polyaddition (both A2+B2 type and AB type) of monomers containing an organic halide and a benzoyl group, a series of phenylmethanol group containing polymers, including polymonophenylmethanol (PMPM), polydiphenylmethanol (PDPM), and polytriphenylmethanol (PTPM), have been synthesized. Para-PTPM exhibits interesting aggregation-induced emission, tunable thermo-responsive over a wide temperature range, sensory, luminescence enhancement of fluorescent dye in solid-state and processing properties. This significantly expands the libraries of monomer and polymer, and opens up an avenue for the design and application of functional polymer materials.

SUBMITTER: Sun XL

PROVIDER: S-EPMC5662735 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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The introduction of the Barbier reaction into polymer chemistry.

Sun Xiao-Li XL Liu Dong-Ming DM Tian Di D Zhang Xiao-Yun XY Wu Wei W Wan Wen-Ming WM

Nature communications 20171031 1

The Barbier reaction, a widely utilized reaction for carbon-carbon bond formation, has played important roles in modern organic chemistry for more than a century. Here, we show its successful introduction to polymer chemistry. Through one-pot Barbier polyaddition (both A2+B2 type and AB type) of monomers containing an organic halide and a benzoyl group, a series of phenylmethanol group containing polymers, including polymonophenylmethanol (PMPM), polydiphenylmethanol (PDPM) ...[more]

PMID: 29084940

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