Ontology highlight
ABSTRACT:
SUBMITTER: Kim YI
PROVIDER: S-EPMC3120388 | biostudies-literature | 2011 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20110525 Pt 6
The structure of the title salt, (C(6)H(8)N)(2)[CuCl(3.4)Br(0.6)], consists of two 3-methyl-pyridinium cations and a distorted tetra-hedral [CuCl(3.4)Br(0.6)](2-) dianion. Substitutional disorder with Br is exhibited for three of the Cl atoms of the anion, giving a mixed chloride/bromide cuprate(II) anion. In the crystal, inter-molecular N-H⋯Cl hydrogen bonds link two cations to one anion, forming a three-ion aggregate. These are connected into a supra-molecular chain along the b axis via π-π in ...[more]