Ontology highlight
ABSTRACT:
SUBMITTER: Ahn JM
PROVIDER: S-EPMC5685493 | biostudies-literature | 2017 Sep
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20170831 36
We have recently reported that a variety of couplings of nitrogen, sulfur, oxygen, and carbon nucleophiles with organic halides can be achieved under mild conditions (-40 to 30 °C) through the use of light and a copper catalyst. Insight into the various mechanisms by which these reactions proceed may enhance our understanding of chemical reactivity and facilitate the development of new methods. In this report, we apply an array of tools (EPR, NMR, transient absorption, and UV-vis spectroscopy; E ...[more]