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ABSTRACT:
SUBMITTER: Kuribayashi S
PROVIDER: S-EPMC5827776 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20180212
We herein report that the regioselective anodic fluorination of <i>S</i>-alkyl benzothioate and its derivatives in various aprotic solvents using Et<sub>3</sub>N·<i>n</i>HF (<i>n</i> = 3-5) and Et<sub>4</sub>NF·<i>n</i>HF (<i>n</i> = 3-5) as supporting electrolyte and a fluorine source successfully provided the corresponding α-fluorinated products in moderate yields. Dichloromethane containing Et<sub>4</sub>NF·4HF was found to be the most suitable combination as electrolytic solvent and supporti ...[more]