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Palladium(III)-catalyzed fluorination of arylboronic acid derivatives.

ABSTRACT: A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.

SUBMITTER: Mazzotti AR 

PROVIDER: S-EPMC3820116 | biostudies-literature | 2013 Sep

REPOSITORIES: biostudies-literature

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Palladium(III)-catalyzed fluorination of arylboronic acid derivatives.

Mazzotti Anthony R AR   Campbell Michael G MG   Tang Pingping P   Murphy Jennifer M JM   Ritter Tobias T  

Journal of the American Chemical Society 20130916 38

A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized. ...[more]

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