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Solubilization of Hydrophobic Catalysts Using Nanoparticle Hosts.

ABSTRACT: A modular strategy for the solubilization and protection of hydrophobic transition metal catalysts using the hydrophobic pockets of water soluble gold nanoparticles is reported. Besides preserving original catalyst activity, this encapsulation strategy provides a protective environment for the hydrophobic catalyst and brings reusability. This system provides a versatile platform for the encapsulation of different hydrophobic transition metal catalysts, allowing a wide range of catalysis in water while uniting the advantages of homogeneous and heterogeneous catalysis in the same system.

SUBMITTER: Jeong Y

PROVIDER: S-EPMC5848072 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Solubilization of Hydrophobic Catalysts Using Nanoparticle Hosts.

Jeong Youngdo Y Tonga Gulen Yesilbag GY Duncan Bradley B Yan Bo B Das Riddha R Sahub Chonticha C Rotello Vincent M VM

Small (Weinheim an der Bergstrasse, Germany) 20171222 7

A modular strategy for the solubilization and protection of hydrophobic transition metal catalysts using the hydrophobic pockets of water soluble gold nanoparticles is reported. Besides preserving original catalyst activity, this encapsulation strategy provides a protective environment for the hydrophobic catalyst and brings reusability. This system provides a versatile platform for the encapsulation of different hydrophobic transition metal catalysts, allowing a wide range of catalysis in water ...[more]

PMID: 29271047

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