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One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid.

ABSTRACT: A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination-oxidation sequence.

SUBMITTER: Soldatova N

PROVIDER: S-EPMC5905280 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature

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One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid.

Soldatova Natalia N Postnikov Pavel P Kukurina Olga O Zhdankin Viktor V VV Yoshimura Akira A Wirth Thomas T Yusubov Mekhman S MS

Beilstein journal of organic chemistry 20180412

A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination-oxidation sequence. ...[more]

PMID: 29719579

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