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Crystal structure of bis-(diiso-propyl-ammonium) cis-di-iodido-bis-(oxolato-κ²O¹,O²)stannate(IV).

ABSTRACT: In the title compound, (ⁱPr₂NH₂)₂[SnI₂(C₂O₄)₂], which was prepared by reacting ( ⁱ Pr₂NH₂⁺)₂·C₂O₄^2- with SnI₄ in a 2:1 molar ratio in a mixed ethanol-aceto-nitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N-H⋯O and bifurcated N-H⋯(O,O) hydrogen bonds, generating [10-1] chains.

SUBMITTER: Sarr B

PROVIDER: S-EPMC5946977 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(diiso-propyl-ammonium) cis-di-iodido-bis-(oxolato-κ2O1,O2)stannate(IV).

Sarr Bougar B Diop Cheikh Abdoul Khadir CAK Sidibé Mamadou M Rousselin Yoann Y

Acta crystallographica. Section E, Crystallographic communications 20180309 Pt 4

In the title compound, (iPr2NH2)2[SnI2(C2O4)2], which was prepared by reacting ( i Pr2NH2+)2·C2O42- with SnI4 in a 2:1 molar ratio in a mixed ethanol-aceto-nitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the c ...[more]

PMID: 29765755

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