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Bis(trimethyl-ammonium) tetra-chlorido-diphenyl-stannate(IV).

ABSTRACT: The title compound, [(CH(3))(3)NH](2)[Sn(C(6)H(5))(2)Cl(4)], consists of [(CH(3))(3)NH](+) cations and [SnPh(2)Cl(4)](2-) anions in which the Sn atom, located on a centre of inversion, is bonded to four Cl atoms and two phenyl rings, giving an octa-hedral geometry with the phenyl rings in trans positions. In the crystal, the cations and the anions are connected by N-H?Cl hydrogen bonds and C-H?Cl inter-actions.

SUBMITTER: Diop T

PROVIDER: S-EPMC3051760 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Bis(trimethyl-ammonium) tetra-chlorido-diphenyl-stannate(IV).

Diop Tidiane T Diop Libasse L Molloy K C Kieran KC Kocioc-Köhn Gabrielle G

Acta crystallographica. Section E, Structure reports online 20110115 Pt 2

The title compound, [(CH(3))(3)NH](2)[Sn(C(6)H(5))(2)Cl(4)], consists of [(CH(3))(3)NH](+) cations and [SnPh(2)Cl(4)](2-) anions in which the Sn atom, located on a centre of inversion, is bonded to four Cl atoms and two phenyl rings, giving an octa-hedral geometry with the phenyl rings in trans positions. In the crystal, the cations and the anions are connected by N-H⋯Cl hydrogen bonds and C-H⋯Cl inter-actions. ...[more]

PMID: 21522868

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