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Crystal structure of hexa-kis-(dimethyl sulfoxide-?O)cobalt(II) bis-[tri-chlorido-(quinoline-?N)cobaltate(II)].

ABSTRACT: There are few reports that describe crystal structures of compounds containing cobalt complexed to either dimethyl sulfoxide (Me2SO) or quinoline (C9H7N). The title compound, [Co(C2H6OS)6][CoCl3(C9H7N)]2, is a cobalt salt in which the metal ion is complexed to both Me2SO and quinoline. In particular, we observed that anhydrous cobalt(II) chloride reacts with quinoline in Me2SO to form a salt that is to be formulated as [CoII(Me2SO)6]2+{[CoIICl3quinoline]2-}. The CoII atom in the cation portion of this mol-ecule lies on a inversion center and is bound to the O atoms of six Me2SO moieties in an octa-hedral configuration, while the CoII atom in the anion is attached to three chloride ligands and one quinoline moiety in a tetra-hedral arrangement.

SUBMITTER: Brescia TK

PROVIDER: S-EPMC5947792 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of hexa-kis-(dimethyl sulfoxide-κO)cobalt(II) bis-[tri-chlorido-(quinoline-κN)cobaltate(II)].

Brescia Tyler K TK Mulosmani Kaltrina K Gulati Shivani S Athanasopoulos Demosthenes D Upmacis Rita K RK

Acta crystallographica. Section E, Crystallographic communications 20180207 Pt 3

There are few reports that describe crystal structures of compounds containing cobalt complexed to either dimethyl sulfoxide (Me2SO) or quinoline (C9H7N). The title compound, [Co(C2H6OS)6][CoCl3(C9H7N)]2, is a cobalt salt in which the metal ion is complexed to both Me2SO and quinoline. In particular, we observed that anhydrous cobalt(II) chloride reacts with quinoline in Me<su ...[more]

PMID: 29765712

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