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Crystal structure of hexa-kis-(dimethyl sulfoxide-?O)manganese(II) tetra-iodide.


ABSTRACT: The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I42- tetra-iodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octa-hedrally coordinated by O atoms of the DMSO mol-ecule with an Mn-O distance of 2.1808?(12)?Å. The I42- anion contains a neutral I2 mol-ecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetra-iodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.

SUBMITTER: Haque MA 

PROVIDER: S-EPMC5137610 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of hexa-kis-(dimethyl sulfoxide-κ<i>O</i>)manganese(II) tetra-iodide.

Haque Md Azimul MA   Davaasuren Bambar B   Rothenberger Alexander A   Wu Tom T  

Acta crystallographica. Section E, Crystallographic communications 20161115 Pt 12


The title salt, [Mn(C<sub>2</sub>H<sub>6</sub>OS)<sub>6</sub>]I<sub>4</sub>, is made up from discrete [Mn(DMSO)<sub>6</sub>]<sup>2+</sup> (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I<sub>4</sub><sup>2-</sup> tetra-iodide anions. The Mn<sup>II</sup> ion in the cation, situated on a position with site symmetry -3., is octa-hedrally coordinated by O atoms of the DMSO mol-ecule with an Mn-O distance of 2.1808 (12) Å. The I<sub>4</sub><sup>2-</sup> ani  ...[more]

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