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Crystal structure of tri-benzyl-bis-(tetra-hydro-furan-?O)lutetium(III).

ABSTRACT: In the title compound, [Lu(C7H7)3(C4H8O)2] (1), the Lu ion is coordinated by three benzyl and two tetra-hydro-furan ligands. Two of the benzyl groups are bonded in a classical ?1-fashion through the methyl-ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl-ene C atom, resulting in a modified trigonal-bipyramidal coordination geometry about the Lu center.

SUBMITTER: Saliu KO

PROVIDER: S-EPMC5956313 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of tri-benzyl-bis-(tetra-hydro-furan-κO)lutetium(III).

Saliu Kuburat O KO Takats Josef J McDonald Robert R

Acta crystallographica. Section E, Crystallographic communications 20180109 Pt 2

In the title compound, [Lu(C7H7)3(C4H8O)2] (1), the Lu ion is coordinated by three benzyl and two tetra-hydro-furan ligands. Two of the benzyl groups are bonded in a classical η1-fashion through the methyl-ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl-ene C atom, resulting in a modified trigonal-bipyramidal coordination geometry about the Lu center. ...[more]

PMID: 29850030

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