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(1,4,7,10,13,16-Hexaoxa-cyclo-octa-decane-?(6) O)bis-(tetra-hydro-furan-?O)potassium bis-[(1,2,3,4-?)-anthracene]cobalt(-I) tetra-hydro-furan monosolvate.

ABSTRACT: The asymmetric unit of the title compound, [K(C12H24O6)(C4H8O)2][Co(C14H10)2]·C4H8O, consists of one cationic potassium complex, one anionic cobalt dianthracene complex and one tetra-hydro-furan solvent mol-ecule. The potassium cation is situated at the centre of an 18-crown-6 mol-ecule and between two tetra-hydro-furan mol-ecules, the latter coordin-ating above and below the mean plane formed by the O atoms of the crown ether mol-ecule. The Co atom is coordinated by eight C atoms of two anthracene mol-ecules in an ?(4) manner. The third free tetra-hydro-furan mol-ecule shows orientational disorder on two partially occupied positions [occupancy ratio 0.561?(8):0.439?(8)].

SUBMITTER: He H

PROVIDER: S-EPMC3914043 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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(1,4,7,10,13,16-Hexaoxa-cyclo-octa-decane-κ(6) O)bis-(tetra-hydro-furan-κO)potassium bis-[(1,2,3,4-η)-anthracene]cobalt(-I) tetra-hydro-furan monosolvate.

He Haiyan H Klein Wilhelm W Fässler Thomas F TF

Acta crystallographica. Section E, Structure reports online 20131207 Pt 1

The asymmetric unit of the title compound, [K(C12H24O6)(C4H8O)2][Co(C14H10)2]·C4H8O, consists of one cationic potassium complex, one anionic cobalt dianthracene complex and one tetra-hydro-furan solvent mol-ecule. The potassium cation is situated at the centre of an 18-crown-6 mol-ecule and between two tetra-hydro-furan mol-ecules, the latter coordin-ating above and below the mean plane formed by the O atoms of the crown ether mol-ecule. The Co atom is coordinated by eight C atoms of two anthrac ...[more]

PMID: 24526959

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