Unknown

Dataset Information

0

Crystal structures of 2,3,8,9,14,15-hexa-methyl-5,6,11,12,17,18-hexa-aza-tri-naphthyl-ene and 2,3,8,9,14,15-hexa-phenyl-5,6,11,12,17,18-hexa-za-tri-naphthyl-ene di-chloro-methane disolvate.

ABSTRACT: The crystal structures of two substituted HATN (hexa-aza-tri-naphthyl-ene) derivatives, namely 2,3,8,9,14,15-hexa-methyl- and 2,3,8,9,14,15-hexa-phenyl-5,6,11,12,17,18- hexa-zatri-naphthyl-ene (HATNMe6 and HATNPh6), are reported. Whereas the structure of the methyl-substituted derivative (HATNMe6) contains no solvent mol-ecules (C30H24N6), the hexa-phenyl-substituted structure (HATNPh6) contains two mol-ecules of di-chloro-methane (C60H36N6·2CH2Cl2). This class of planar bridging ligands is known for its electron-deficient systems and its ability to form ?-? stacking inter-actions. Indeed, in both crystal structures strong ?-? stacking inter-actions are observed, but with different packing features. The di-chloro-methane mol-ecules in the crystal structure of HATNPh6 are situated in the voids and are involved in C-H?N contacts to the nitro-gen atoms of the pyrazine units.

SUBMITTER: Fangmann P 

PROVIDER: S-EPMC5956329 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structures of 2,3,8,9,14,15-hexa-methyl-5,6,11,12,17,18-hexa-aza-tri-naphthyl-ene and 2,3,8,9,14,15-hexa-phenyl-5,6,11,12,17,18-hexa-za-tri-naphthyl-ene di-chloro-methane disolvate.

Fangmann Pia P   Schmidtmann Marc M   Beckhaus Rüdiger R  

Acta crystallographica. Section E, Crystallographic communications 20180116 Pt 2

The crystal structures of two substituted HATN (hexa-aza-tri-naphthyl-ene) derivatives, namely 2,3,8,9,14,15-hexa-methyl- and 2,3,8,9,14,15-hexa-phenyl-5,6,11,12,17,18- hexa-zatri-naphthyl-ene (HATNMe<sub>6</sub> and HATNPh<sub>6</sub>), are reported. Whereas the structure of the methyl-substituted derivative (HATNMe<sub>6</sub>) contains no solvent mol-ecules (C<sub>30</sub>H<sub>24</sub>N<sub>6</sub>), the hexa-phenyl-substituted structure (HATNPh<sub>6</sub>) contains two mol-ecules of di-chl  ...[more]

Similar Datasets

Unknown 4-Phenyl-1,2,4-tri-aza-spiro-[4.6]undec-1-ene-3-thione.
| S-EPMC4051002 | biostudies-literature
Unknown 4-Phenyl-1,2,4-tri-aza-spiro-[4.5]dec-1-ene-3-thione.
| S-EPMC3793756 | biostudies-literature
Unknown 4-Phenyl-1,2,4-tri-aza-spiro-[4.4]non-1-ene-3-thione.
| S-EPMC3998538 | biostudies-literature
Unknown 12-(4-Chloro-phen-yl)-7-methyl-10-phenyl-3,4,5,6,8,10-hexa-aza-tricyclo-[7.3.0.0]dodeca-1(9),2,4,7,11-penta-ene.
| S-EPMC3011633 | biostudies-literature
Unknown 6,6'-Dimeth-oxy-2,2'-[p-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenol chloro-form disolvate.
| S-EPMC2969051 | biostudies-literature
Unknown Crystal structure of bis-(N-tert-butyl-benzamidinium) hexa-chlorido-zirconate(IV) di-chloro-methane disolvate.
| S-EPMC4910352 | biostudies-literature
Unknown (Z)-6-[(5-Chloro-2-hydroxy-phenyl)-aminomethyl-ene]-2-ethoxy-cyclo-hexa-2,4-dienone.
| S-EPMC2970131 | biostudies-literature
Unknown 1,3-Phenyl-ene bis-{3-[2-chloro-4-(tri-fluoro-meth-yl)phen-oxy]benzoate}.
| S-EPMC3414352 | biostudies-literature
Unknown Synthesis and crystal structure of tri-ethyl-ammonium hexa-bromido-uranate(IV) di-chloro-methane monosolvate.
| S-EPMC7534249 | biostudies-literature
Unknown Crystal structure of octa-μ3-selenido-(p-toluene-sulfonato-κO)penta-kis-(tri-ethyl-phosphane-κP)-octa-hedro-hexa-rhenium(III) p-toluene-sulfonate di-chloro-methane disolvate.
| S-EPMC4555408 | biostudies-literature