Ontology highlight
ABSTRACT:
SUBMITTER: Shen X
PROVIDER: S-EPMC5969497 | biostudies-literature | 2018 May
REPOSITORIES: biostudies-literature
Shen Xiang X Li Yanjun Y Wen Zhaorui Z Cao Shi S Hou Xinyi X Gong Lei L
Chemical science 20180427 20
The enantioselective photoredox reaction of α,β-unsaturated carbonyl compounds and tertiary/secondary α-silylamines was enabled by a readily available single Ni<sup>II</sup>-DBFOX catalyst (DBFOX = 4,6-bis((<i>R</i>)-4-phenyl-4,5-dihydrooxazol-2-yl)dibenzo[<i>b</i>,<i>d</i>]furan) under visible light conditions. The non-precious chiral catalyst is involved in the photochemical process to initiate single electron transfer and at the same time provides a well-organized chiral environment for the s ...[more]