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Design of oligothiophene-based tetrazoles for laser-triggered photoclick chemistry in living cells.

ABSTRACT: A 405 nm light-activatable terthiophene-based tetrazole was designed that reacts with a fumarate dipolarophile with the second-order rate constant k2 exceeding 10(3) M(-1) s(-1). The utility of this laser-activatable tetrazole in imaging microtubules in a spatiotemporally controlled manner in live cells was demonstrated.

SUBMITTER: An P 

PROVIDER: S-EPMC3847902 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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Design of oligothiophene-based tetrazoles for laser-triggered photoclick chemistry in living cells.

An Peng P   Yu Zhipeng Z   Lin Qing Q  

Chemical communications (Cambridge, England) 20131101 85

A 405 nm light-activatable terthiophene-based tetrazole was designed that reacts with a fumarate dipolarophile with the second-order rate constant k2 exceeding 10(3) M(-1) s(-1). The utility of this laser-activatable tetrazole in imaging microtubules in a spatiotemporally controlled manner in live cells was demonstrated. ...[more]

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