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Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation.

ABSTRACT: Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

SUBMITTER: Deria P 

PROVIDER: S-EPMC6088556 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Water stabilization of Zr<sub>6</sub>-based metal-organic frameworks <i>via</i> solvent-assisted ligand incorporation.

Deria Pravas P   Chung Yongchul G YG   Snurr Randall Q RQ   Hupp Joseph T JT   Farha Omar K OK  

Chemical science 20150701 9

Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs. ...[more]

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