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Hydrogen Peroxide-Treated Carbon Dot Phosphor with a Bathochromic-Shifted, Aggregation-Enhanced Emission for Light-Emitting Devices and Visible Light Communication.


ABSTRACT: It is demonstrated that treatment of blue-emissive carbon dots (CDs) with aqueous hydrogen peroxide (H2O2) results in the green emissive solid state CD phosphor with photoluminescence quantum yield of 25% and short luminescence lifetime of 6 ns. The bathochromic-shifted, enhanced green emission of H2O2-treated CDs in the powder is ascribed to surface state changes occurring in the aggregated material. Using the green emissive H2O2-treated CD phosphor, down-conversion white-light-emitting devices with cool, pure, and warm white light are fabricated. Moreover, using the green emissive CD phosphor as a color converter, a laser-based white-light source is realized, and visible light communication with a high modulation bandwidth of up to 285 MHz and data transmission rate of ?435 Mbps is demonstrated.

SUBMITTER: Zhou Z 

PROVIDER: S-EPMC6097149 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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Hydrogen Peroxide-Treated Carbon Dot Phosphor with a Bathochromic-Shifted, Aggregation-Enhanced Emission for Light-Emitting Devices and Visible Light Communication.

Zhou Zhengjie Z   Tian Pengfei P   Liu Xiaoyan X   Mei Shiliang S   Zhou Ding D   Li Di D   Jing Pengtao P   Zhang Wanlu W   Guo Ruiqian R   Qu Songnan S   Rogach Andrey L AL  

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20180613 8


It is demonstrated that treatment of blue-emissive carbon dots (CDs) with aqueous hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) results in the green emissive solid state CD phosphor with photoluminescence quantum yield of 25% and short luminescence lifetime of 6 ns. The bathochromic-shifted, enhanced green emission of H<sub>2</sub>O<sub>2</sub>-treated CDs in the powder is ascribed to surface state changes occurring in the aggregated material. Using the green emissive H<sub>2</sub>O<sub>2</sub>  ...[more]

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