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Rhodium(iii)-catalyzed C-H allylation of indoles with allyl alcohols via ?-hydroxide elimination.
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ABSTRACT:
SUBMITTER: Wu X
PROVIDER: S-EPMC6135611 | biostudies-literature | 2018 Aug
REPOSITORIES: biostudies-literature
Publications
Rhodium(iii)-catalyzed C-H allylation of indoles with allyl alcohols via β-hydroxide elimination.
Organic & biomolecular chemistry 20180801 31
An efficient Rh(iii)-catalyzed dehydrative C-H allylation of indoles with allyl alcohols via β-hydroxide elimination under oxidant-free conditions has been developed. This method features very mild reaction conditions, excellent regioselectivity and stereoselectivity, and compatibility with various functional groups. In addition, the directing group can be removed under mild reaction conditions, which further underscores the synthetic utility of this method. ...[more]