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Crystal structure of (E)-2-[3-(tert-but-yl)-2-hy-droxy-benzyl-idene]-N-cyclo-hexyl-hydrazine-1-carbo-thio-amide.

ABSTRACT: In the title compound, C18H27N3OS, the cyclo-hexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbo-thio-amide moiety and substituted benzene ring are twisted by 31.13?(5)° relative to each other. The amide moiety and the cyclo-hexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, mol-ecules are linked by N-H?S hydrogen bonds, forming inversion dimers with an R 2 2(8) ring motif.

SUBMITTER: Arafath MA 

PROVIDER: S-EPMC6176448 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of (<i>E</i>)-2-[3-(<i>tert</i>-but-yl)-2-hy-droxy-benzyl-idene]-<i>N</i>-cyclo-hexyl-hydrazine-1-carbo-thio-amide.

Arafath Md Azharul MA   Kwong Huey Chong HC   Adam Farook F   Razali Mohd R MR  

Acta crystallographica. Section E, Crystallographic communications 20180921 Pt 10

In the title compound, C<sub>18</sub>H<sub>27</sub>N<sub>3</sub>OS, the cyclo-hexane ring has a chair conformation. The azomethine C=N double bond has an <i>E</i> configuration. The nearly planar hydrazinecarbo-thio-amide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclo-hexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, mol-ecules are linked  ...[more]

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