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2-Cyclo-heptyl-idene-N-phenyl-hydrazine-carbo-thio-amide.

ABSTRACT: In the title compound, C14H19N3S, the seven-membered cyclo-heptane ring adopts a chair conformation. An intra-molecular N-H?N hydrogen bond [graph-set motif S(5)] is present in the N-N-C-N chain between the ring systems. An intra-molecular C-H?S contact also occurs. In the crystal, pairs of mol-ecules form centrosymmetric dimers through N-H?S hydrogen bonds [graph-set R 2 (2)(8)]. These dimers are connected by C-H?S inter-actions with an R 2 (2)(14) motif.

SUBMITTER: Akkurt M

PROVIDER: S-EPMC3998488 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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2-Cyclo-heptyl-idene-N-phenyl-hydrazine-carbo-thio-amide.

Akkurt Mehmet M Mohamed Shaaban K SK Mague Joel T JT Hassan Alaa A AA Albayati Mustafa R MR

Acta crystallographica. Section E, Structure reports online 20140226 Pt 3

In the title compound, C14H19N3S, the seven-membered cyclo-heptane ring adopts a chair conformation. An intra-molecular N-H⋯N hydrogen bond [graph-set motif S(5)] is present in the N-N-C-N chain between the ring systems. An intra-molecular C-H⋯S contact also occurs. In the crystal, pairs of mol-ecules form centrosymmetric dimers through N-H⋯S hydrogen bonds [graph-set R 2 (2)(8)]. These dimers are connected by C-H⋯S inter-actions with an R 2 (2)(14) motif. ...[more]

PMID: 24765045

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