Unknown

Dataset Information

0

Intermolecular Markovnikov-Selective Hydroacylation of Olefins Catalyzed by a Cationic Ruthenium-Hydride Complex.

ABSTRACT: The cationic Ru-H complex was found to be an effective catalyst for the intermolecular hydroacylation of aryl-substituted olefins with aldehydes to form branched ketone products. The preliminary kinetic and spectroscopic studies elucidated a ruthenium-acyl complex as the key intermediate species. The catalytic method directly afforded branched ketone products in a highly regioselective manner while tolerating a number of heteroatom functional groups.

SUBMITTER: Kim J 

PROVIDER: S-EPMC6261526 | biostudies-literature | 2016 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Intermolecular Markovnikov-Selective Hydroacylation of Olefins Catalyzed by a Cationic Ruthenium-Hydride Complex.

Kim Junghwa J   Yi Chae S CS  

ACS catalysis 20160419 5

The cationic Ru-H complex was found to be an effective catalyst for the intermolecular hydroacylation of aryl-substituted olefins with aldehydes to form branched ketone products. The preliminary kinetic and spectroscopic studies elucidated a ruthenium-acyl complex as the key intermediate species. The catalytic method directly afforded branched ketone products in a highly regioselective manner while tolerating a number of heteroatom functional groups. ...[more]

Similar Datasets

Unknown Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C-H Bond Activation Catalyzed by an In-Situ Formed Cationic Ruthenium-Hydride Complex.
| S-EPMC2805103 | biostudies-literature
Unknown Direct Intermolecular Anti-Markovnikov Hydroazidation of Unactivated Olefins.
| S-EPMC6677148 | biostudies-literature
Unknown Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation.
| S-EPMC2887707 | biostudies-literature
Unknown Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins.
| S-EPMC6986200 | biostudies-literature
Unknown Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles.
| S-EPMC5386394 | biostudies-literature
Unknown Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines.
| S-EPMC2739117 | biostudies-literature
Unknown Schiff Base Cobalt(II) Complex-Catalyzed Highly Markovnikov-Selective Hydrosilylation of Alkynes.
| S-EPMC7875507 | biostudies-literature
Unknown Chain- and Regioselective Ethylene and Styrene Dimerization Reactions Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: New Insights on the Styrene Dimerization Mechanism.
| S-EPMC2915581 | biostudies-literature
Unknown Rh(I)-catalyzed intermolecular hydroacylation: enantioselective cross-coupling of aldehydes and ketoamides.
| S-EPMC4091274 | biostudies-literature
Unknown Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition.
| S-EPMC2532823 | biostudies-literature