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ABSTRACT:
SUBMITTER: Yamada M
PROVIDER: S-EPMC6264206 | biostudies-literature | 2011 Nov
REPOSITORIES: biostudies-literature
Yamada Michio M Someya Chika I CI Nakahodo Tsukasa T Maeda Yutaka Y Tsuchiya Takahiro T Akasaka Takeshi T
Molecules (Basel, Switzerland) 20111114 11
Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La(2)@I(h)-C(80). NMR spectroscopic studies revealed that the glycoconjugate consists of two diastereomers of [6,6]-open mono-adducts. The electronic properties were characterized using Vis/NIR absorption spectroscopy and electrochemical measurements. This study demonstrates that glycosylidene carbene is useful to incorporate carbohydrate m ...[more]