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Crystal structure of di-?-hydroxido-bis-{aqua-[ethyl (1,10-phenanthrolin-3-yl)phospho-nato-?2 N,N']copper(II)} hepta-hydrate.

ABSTRACT: In the title compound, [Cu2(OH)2{C12H7N2(PO3C2H5)}2(H2O)2]·7H2O, two Cu2+ cations are bridged by two hydroxide groups, forming a centrosymmetric binuclear complex. Each Cu2+cation is further coordinated by the N atoms of a bidentate ethyl (1,10-phenanthrolin-3-yl)phospho-nate anion and a water mol-ecule in a square-pyramidal geometry. In the crystal, a network of O-H?O hydrogen bonds involving the P(O)(O-)(OEt) groups, bridging hydroxyl groups, coordinated and uncoordinated water mol-ecules generates a three-dimensional supra-molecular structure. The ethyl group exhibits disorder and was modelled over three sites with occupancies of 0.455, 0.384 and 0.161.

SUBMITTER: Mitrofanov AY

PROVIDER: S-EPMC6281120 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of di-μ-hydroxido-bis-{aqua-[ethyl (1,10-phenanthrolin-3-yl)phospho-nato-κ2 N,N']copper(II)} hepta-hydrate.

Mitrofanov Alexander Yu AY Rousselin Yoann Y

Acta crystallographica. Section E, Crystallographic communications 20181109 Pt 12

In the title compound, [Cu2(OH)2{C12H7N2(PO3C2H5)}2(H2O)2]·7H2O, two Cu2+ cations are bridged by two hydroxide groups, forming a centrosymmetric binuclear complex. Each Cu2+cation is further coordinated by the N atoms of a bidentate ethyl (1,10-phenanthrolin-3-yl)phospho-nate anion and a water mol-ecule in a square-pyramidal geometry. In the cr ...[more]

PMID: 30574368

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