Dataset Information
Bronsted acid-catalyzed aromatic annulation of alkoxyallenes with naphthols: a reaction sequence to larger ?-conjugated naphthopyrans with aggregation-induced emission characters.
Ontology highlight
ABSTRACT:
SUBMITTER: Zhang J
PROVIDER: S-EPMC6346396 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Publications
Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with naphthols: a reaction sequence to larger π-conjugated naphthopyrans with aggregation-induced emission characters.
Chemical science 20181102 4
A practical and readily scalable reaction sequence was developed for the straightforward synthesis of a new family of larger π-conjugated naphthopyrans by a Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with inert naphthols. The cascade pathway involves allylation/cyclization/debenzyloxylation/isomerization/dehydration. The new class of solid state diphenylmethylene substituted naphthopyrans are fluorescent emissive and proved to have aggregation-induced emission (AIE) behavior. ...[more]