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Crystal structure of bis(4-benzoyl-pyridine-?N)bis(methanol-?O)bis(thio-cyanato-?N)nickel(II) methanol monosolvate.

ABSTRACT: The asymmetric unit of the title compound, [Ni(NCS)2(C12H9NO)2(CH3OH)2]·CH3OH, comprises one NiII cation, two thio-cyanate anions, two 4-benzoyl-pyridine coligands, two coordinating, as well as one non-coordinating methanol mol-ecule. The NiII cation is coordinated by two terminally N-bonded thio-cyanate anions, the N atoms of two 4-benzoyl-pyridine coligands and the O atoms of two methanol ligands within a slightly distorted octa-hedron. Individual complexes are linked by inter-molecular O-H?S hydrogen bonding into chains parallel to [010] that are further connected into layers parallel to (10) by C-H?S hydrogen bonds. Additional C-H?O hydrogen-bonding inter-actions lead to the formation of a three-dimensional network that limits channels extending parallel to [010] in which the non-coordinating methanol mol-ecules are located. They are hydrogen-bonded to the coordinating methanol mol-ecules. X-ray powder diffraction revealed that the compound could not be prepared as a pure phase.

SUBMITTER: Wellm C 

PROVIDER: S-EPMC6362648 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of bis(4-benzoyl-pyridine-κ<i>N</i>)bis(methanol-κ<i>O</i>)bis(thio-cyanato-κ<i>N</i>)nickel(II) methanol monosolvate.

Wellm Carsten C   Näther Christian C  

Acta crystallographica. Section E, Crystallographic communications 20190131 Pt 2

The asymmetric unit of the title compound, [Ni(NCS)<sub>2</sub>(C<sub>12</sub>H<sub>9</sub>NO)<sub>2</sub>(CH<sub>3</sub>OH)<sub>2</sub>]·CH<sub>3</sub>OH, comprises one Ni<sup>II</sup> cation, two thio-cyanate anions, two 4-benzoyl-pyridine coligands, two coordinating, as well as one non-coordinating methanol mol-ecule. The Ni<sup>II</sup> cation is coordinated by two terminally N-bonded thio-cyanate anions, the N atoms of two 4-benzoyl-pyridine coligands and the O atoms of two methanol ligands  ...[more]

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