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Crystal structure of bis-(3,5-di-methyl-pyridine-?N)bis-(methanol-?O)bis-(thio-cyanato-?N)cobalt(II).

ABSTRACT: The asymmetric unit of the title complex, [Co(NCS)₂(C₇H₉N)₂(CH₃OH)₂], comprises of one Co^II cation located on a centre of inversion, one thio-cyanate ligand, one methanol ligand and one 3,5-di-methyl-pyridine ligand. The Co^II cation is octa-hedrally coordinated by two terminal N-bonding thio-cyanate anions, two methanol mol-ecules and two 3,5-di-methyl-pyridine ligands into a discrete complex. The complex mol-ecules are linked by inter-molecular O-H?S hydrogen bonding into chains that elongate in the direction parallel to the b axis.

SUBMITTER: Suckert S

PROVIDER: S-EPMC5137618 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(3,5-di-methyl-pyridine-κN)bis-(methanol-κO)bis-(thio-cyanato-κN)cobalt(II).

Suckert Stefan S Jess Inke I Näther Christian C

Acta crystallographica. Section E, Crystallographic communications 20161118 Pt 12

The asymmetric unit of the title complex, [Co(NCS)2(C7H9N)2(CH3OH)2], comprises of one CoII cation located on a centre of inversion, one thio-cyanate ligand, one methanol ligand and one 3,5-di-methyl-pyridine ligand. The CoII cation is octa-hedrally coordinated by two terminal N-bonding thio-cyanate anions, two methanol mol-ecules and two 3,5-di-methyl-pyridine ligands into a discrete complex. The complex mol ...[more]

PMID: 27980840

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