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Block copolymer derived uniform mesopores enable ultrafast electron and ion transport at high mass loadings.

ABSTRACT: High mass loading and fast charge transport are two crucial but often mutually exclusive characteristics of pseudocapacitors. On conventional carbon supports, high mass loadings inevitably lead to sluggish electron conduction and ion diffusion due to thick pseudocapacitive layers and clogged pores. Here we present a design principle of carbon supports, utilizing self-assembly and microphase-separation of block copolymers. We synthesize porous carbon fibers (PCFs) with uniform mesopores of 11.7?nm, which are partially filled with MnO2 of <2?nm in thickness. The uniform mesopores and ultrathin MnO2 enable fast electron/ion transport comparable to electrical-double-layer-capacitive carbons. At mass loadings approaching 7?mg?cm-2, the gravimetric and areal capacitances of MnO2 (~50% of total mass) reach 1148 F g-1 and 3141 mF cm-2, respectively. Our MnO2-coated PCFs outperform other MnO2-based electrodes at similar loadings, highlighting the great promise of block copolymers for designing PCF supports for electrochemical applications.

SUBMITTER: Liu T

PROVIDER: S-EPMC6368586 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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Block copolymer derived uniform mesopores enable ultrafast electron and ion transport at high mass loadings.

Liu Tianyu T Zhou Zhengping Z Guo Yichen Y Guo Dong D Liu Guoliang G

Nature communications 20190208 1

High mass loading and fast charge transport are two crucial but often mutually exclusive characteristics of pseudocapacitors. On conventional carbon supports, high mass loadings inevitably lead to sluggish electron conduction and ion diffusion due to thick pseudocapacitive layers and clogged pores. Here we present a design principle of carbon supports, utilizing self-assembly and microphase-separation of block copolymers. We synthesize porous carbon fibers (PCFs) with uniform mesopores of 11.7 n ...[more]

PMID: 30737399

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Project description:Understanding protein-surface interactions is crucial to solid-state biomedical applications whose functionality is directly correlated with the precise control of the adsorption configuration, surface packing, loading density, and bioactivity of protein molecules. Because of the small dimensions and highly amphiphilic nature of proteins, investigation of protein adsorption performed on nanoscale topology can shed light on subprotein-level interaction preferences. In this study, we examine the adsorption and assembly behavior of a highly elongated protein, fibrinogen, on both chemically uniform (as-is and buffered HF-treated SiO2/Si, and homopolymers of polystyrene and poly(methyl methacrylate)) and varying (polystyrene-block-poly(methyl methacrylate)) surfaces. By focusing on high-resolution imaging of individual protein molecules whose configurations are influenced by protein-surface rather than protein-protein interactions, fibrinogen conformations characteristic to each surface are identified and statistically analyzed for structural similarities/differences in key protein domains. By exploiting block copolymer nanodomains whose repeat distance is commensurate with the length of the individual protein, we determine that fibrinogen exhibits a more neutral tendency for interaction with both polystyrene and poly(methyl methacrylate) blocks relative to the case of common globular proteins. Factors affecting fibrinogen-polymer interactions are discussed in terms of hydrophobic and electrostatic interactions. In addition, assembly and packing attributes of fibrinogen are determined at different loading conditions. Primary orientations of fibrinogen and its rearrangements with respect to the underlying diblock nanodomains associated with different surface coverage are explained by pertinent protein interaction mechanisms. On the basis of two-dimensional stacking behavior, a protein assembly model is proposed for the formation of an extended fibrinogen network on the diblock copolymer.

Dataset Information

Block copolymer derived uniform mesopores enable ultrafast electron and ion transport at high mass loadings.

Publications

Block copolymer derived uniform mesopores enable ultrafast electron and ion transport at high mass loadings.

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