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A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity.

ABSTRACT: A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by ¹ H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.

SUBMITTER: Neniskis A

PROVIDER: S-EPMC6391958 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity.

Neniškis Algirdas A Račkauskaitė Dovilė D Shi Qixun Q Robertson Aiden J AJ Marsh Andrew A Ulčinas Artūras A Valiokas Ramūnas R Brown Steven P SP Wärnmark Kenneth K Orentas Edvinas E

Chemistry (Weinheim an der Bergstrasse, Germany) 20180906 53

A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by <sup>1</sup> H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications. ...[more]

PMID: 30070741

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