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ABSTRACT:
SUBMITTER: Polyanskii KB
PROVIDER: S-EPMC6399687 | biostudies-literature | 2019 Mar
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20190208 Pt 3
The title compound, [RuCl<sub>2</sub>(C<sub>21</sub>H<sub>26</sub>N<sub>2</sub>)(C<sub>11</sub>H<sub>15</sub>N)], is an example of a new generation of <i>N</i>,<i>N</i>-dialkyl metallocomplex ruthenium catalysts with an N→Ru coordination bond as part of a six-membered chelate ring. The Ru atom has an Addison τ parameter of 0.234, which indicates a geometry inter-mediate between square-based pyramidal and trigonal-bipyramidal. The complex shows the usual <i>trans</i> arrangement of the two chlori ...[more]