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Di-?(2)-chlorido-bis-[chlorido(?-hexa-methyl-benzene)ruthenium(II)].

ABSTRACT: Dimeric mol-ecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one mol-ecule in the asymmetric unit. The hexa-methyl-benzene rings are in an ?(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In addition, the ruthenium centres are bonded to another chloride ligand. The aromatic rings and the Ru(2)Cl(2) four-membered ring enclose a dihedral angle of 55.85?(6)°.

SUBMITTER: Gonzalez-Torres Y

PROVIDER: S-EPMC2971002 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Di-μ(2)-chlorido-bis-[chlorido(η-hexa-methyl-benzene)ruthenium(II)].

González-Torres Yunuem Y Espinosa-Jalapa Noel N Hernández-Ortega Simón S Le Lagadec Ronan R Morales-Morales David D

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

Dimeric mol-ecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one mol-ecule in the asymmetric unit. The hexa-methyl-benzene rings are in an η(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In addition, the ruthenium centres are bonded to another chloride ligand. The aromatic rings and the Ru(2)Cl(2) four-membered ring enclose a dihedral angle of 55.85 (6)°. ...[more]

PMID: 21578121

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