Unknown

Dataset Information

0

Crystal structure and Hirshfeld surfaces analysis of the nickel(II) complex of the Shiff base ligand 6,6'-{(1E,1'E)-[ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-[2-(tri-fluoro-meth-oxy)phenol].

ABSTRACT: In the title complex, (6,6'-{(1E,1'E)-[ethane-1,2-diylbis(aza-nylyl-idene)]bis(methanylyl-idene)}bis-[2-(tri-fluoro-meth-oxy)phenol]-?4 O,N,N',O')nickel(II), [Ni(C18H12F6N2O4)], the nickel(II) ion has a square-planar coordination sphere, being ligated by two N and two O atoms of the Schiff base ligand 6,6'-{(1E,1'E)-[ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-[2-(tri-fluoro-meth-oxy)phenol] (L). Inversion-related mol-ecules are linked by a short Ni?Ni inter-action of 3.2945?(6)?Å forming a dimer. In the crystal, the dimers stack up the a axis, with a closest Ni?Ni separation of ca 3.791?Å. There are no other significant inter-molecular inter-actions present. However, the Hirshfeld surface analysis and the two-dimensional fingerprint plots indicate that the packing is dominated by H?F/F?H, H?H, O?H/H?O and C?H/H?C contacts.

SUBMITTER: Demir Kanmazalp S 

PROVIDER: S-EPMC6399694 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure and Hirshfeld surfaces analysis of the nickel(II) complex of the Shiff base ligand 6,6'-{(1<i>E</i>,1'<i>E</i>)-[ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-[2-(tri-fluoro-meth-oxy)phenol].

Demir Kanmazalp Sibel S   Meral Seher S   Dege Necmi N   Alaman Agar Aysen A   Fritsky Igor O IO  

Acta crystallographica. Section E, Crystallographic communications 20190208 Pt 3

In the title complex, (6,6'-{(1<i>E</i>,1'<i>E</i>)-[ethane-1,2-diylbis(aza-nylyl-idene)]bis(methanylyl-idene)}bis-[2-(tri-fluoro-meth-oxy)phenol]-κ<sup>4</sup> <i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>')nickel(II), [Ni(C<sub>18</sub>H<sub>12</sub>F<sub>6</sub>N<sub>2</sub>O<sub>4</sub>)], the nickel(II) ion has a square-planar coordination sphere, being ligated by two N and two O atoms of the Schiff base ligand 6,6'-{(1<i>E</i>,1'<i>E</i>)-[ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}  ...[more]

Similar Datasets

Unknown Crystal structure and Hirshfeld surface analysis of 2,2'-{(1E,1'E)-[ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-[4-(tri-fluoro-meth-oxy)phenol]copper(II) hydro-quinone hemisolvate.
| S-EPMC6829737 | biostudies-literature
Unknown Di-aqua-{2,2'-dimeth-oxy-6,6'-[(1E,1'E)-propane-1,3-diylbis(aza-nylyl-idene)bis-(methanylyl-idene)]diphenolato}nickel(II).
| S-EPMC3772429 | biostudies-literature
Unknown 4,4',6,6'-Tetra-bromo-2,2'-[(E,E)-ethane-1,2-diylbis(nitrilo-methanylyl-idene)]di-phenol.
| S-EPMC3414283 | biostudies-literature
Unknown Crystal structure, Hirshfeld surface analysis and anti-oxidant capacity of 2,2'-{(1E,1'E)-[1,2-phenyl-enebis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-(5-benz-yloxy)phenol.
| S-EPMC5947487 | biostudies-literature
Unknown Crystal structure of di-?-acetato-di-acetatobis-(?-6,6'-dimeth-oxy-2,2'-{[(propane-1,3-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}diphenolato)tetra-zinc.
| S-EPMC4719841 | biostudies-other
Unknown Crystal structure and Hirshfeld surface analysis of 6,6'-((1<i>E</i>,1'<i>E</i>)-{[1,4-phenyl-enebis(methyl-ene)]bis(aza-nylyl-idene)}bis-(methane-ylyl-idene))bis-(2-meth-oxy-phenol).
| S-EPMC8739199 | biostudies-literature
Unknown {6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II) dimethyl-formamide monosolvate.
| S-EPMC3051997 | biostudies-literature
Unknown 6,6'-[(1E,1'E)-Oxybis(4,1-phenyl-ene)bis-(aza-nylyl-idene)bis-(methanylyl-idene)]bis-(2-methyl-phenol): supra-molecular assemblies in two dimensions mediated by weak C-H?N, C-H?O and C-H?? inter-actions.
| S-EPMC5947488 | biostudies-literature
Unknown Acetato(aqua){6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}cobalt(III) methanol disolvate.
| S-EPMC3393214 | biostudies-literature
Unknown Aqua-{6,6'-dieth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methanylyl-idene)]diphen-olato}zinc.
| S-EPMC3200652 | biostudies-literature