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Orthogonal shortwave infrared emission based on rare earth nanoparticles for interference-free logical codes and bio-imaging.

ABSTRACT: Shortwave infrared (SWIR) photoluminescence has received intense interest in many fields in recent years thanks to the advantages of its wide wavelength range and high tissue imaging ability and it is invisible to the naked eye. However, achieving orthogonal SWIR emission still remains a challenge. In the present study, synthesized NaErF₄@NaLuF₄ (Er@Lu) and NaYF₄:Nd@NaLuF₄ (Y:Nd@Lu) nanoparticles emitted atom-like SWIR emission, and the separation distance between the SWIR emission was beyond 50 nm, which permitted orthogonal SWIR signal acquirement with optical filters. Furthermore, an invisible logical code was designed by manipulating the orthogonal SWIR emission of the lanthanide fluoride nanoparticles, and was further operated by basic logical operations and applied in information encryption and anti-counterfeit fields. In addition, the emission between these two hydrophilic nanoparticles could also be separated in vivo without signal interference and the orthogonal SWIR imaging mode was achieved, which was demonstrated in a bio-imaging experiment in vivo. This demonstration extended the orthogonal SWIR emission capacity by controlling the orthogonal emission, opening new opportunities in the fields of data security, disease diagnosis and non-interference label in vivo.

SUBMITTER: Ma BL

PROVIDER: S-EPMC6429594 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature

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Project description:Several complexes of "PtL2" composition containing two cyanoxime anions - 2-oximino-2-cyano-N-piperidineacetamide (PiPCO-) and 2-oximino-2-cyano-N-morpholylacetamide (MCO-) - have been obtained and characterized both in solution and in the solid state. Complexes exist as two distinct polymorphs: monomeric yellow complexes and dark-green [PtL2]n 1D polymers, while for the MCO- anion a red, solvent containing dimeric [Pt(MCO)2·DMSO]2 complex has also been isolated. The interconversion of polymorphs was investigated. The monomeric PtL2 units are arranged into anisotropic extended solid [PtL2]n polymers with the help of PtPt metallophilic interactions. Crystal structures of monomeric PtL2 (L = PiPCO-, MCO-) and red dimeric [Pt(MCO)2·DMSO]2 complexes were determined and revealed the cis-arrangement of cyanoxime anions. The Pt-Pt distance in the "head-to-tail" red dimer was found to be 3.133 Å. The structure of the polymeric [Pt(PiPCO)2]n compound was elucidated using the EXAFS method and evidenced the formation of Pt-wires with ∼3.15 Å intermetallic separation. The EPR spectra of both 1D polymers at variable temperatures indicate the absence of Pt(iii) species. Both pure dark-green [PtL2]n polymers showed a considerable room temperature electrical conductivity of 20-30 S cm-1, which evidences the formation of a mixed valence Pt(ii)/Pt(iv) system. We discovered that these 1D polymeric [PtL2]n complexes show an intense NIR fluorescence beyond 1000 nm, while yellow monomeric PtL2 complexes are not emissive at all. The room temperature excitation spectra of 1D polymeric [PtL2]n complexes demonstrated their strong emission beyond 1000 nm regardless of the used excitation wavelength between 350 and 800 nm, which is typical of systems with delocalized charge carriers. For the first time the formation of mixed valence "metal wires" held together by metallophilic interactions is directly linked both with an intense fluorescence in the NIR region of the spectrum and with the electrical conductivity. The effect of the concentration of [PtL2]n complexes dispersed in the dielectric salt matrix on the photoluminescence wavelength and intensity was investigated. Both polymers show a quantum yield that is remarkably high for this region of the spectrum, reaching ∼2%. Variable temperature emission of polymeric [PtL2]n in the -190-+60 °C range was studied as well.

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Orthogonal shortwave infrared emission based on rare earth nanoparticles for interference-free logical codes and bio-imaging.

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