Dataset Information

New Organic/Inorganic Pigments Based on Azo Dye and Aluminum-Magnesium Hydroxycarbonates with Various Mg/Al Ratios.

ABSTRACT: This study set out to investigate the impact of aluminum-magnesium hydroxycarbonates (LHs) with various Mg/Al ratios on the formation of hybrid pigments. The colorants were also evaluated for their flame-retardant properties. In the first part of the study, the hybrid pigments were submitted to comprehensive characterization using time-of-flight secondary ion mass spectrometry (TOF-SIMS), ²⁷Al solid-state nuclear magnetic resonance (NMR) spectroscopy, powder X-ray diffraction analysis (XRD), thermogravimetric analysis (TGA), and N₂ adsorption as well as scanning and transmission electron microscopy (SEM/STEM). The relationship between the Mg/Al ratios of the LH carriers and the formation of lake pigments was explored. The TOF-SIMS spectrum of LH modified with azo chromophore (AC) showed an intense peak for the C₁₉H₁₅O₅N₂Mg⁺ ion, confirming metal-dye interactions. Incorporation of the organic colorant into the LH host enhanced its resistance to dissolution in organic solvent (butyl acetate), as well as improving its color stability under elevated temperatures. The second part of the study evaluated the flammability of ethylene-norbornene (EN) composites, in which the pigments had been applied as colorants. Cone calorimetry revealed that addition of the organic-inorganic pigments resulted in a substantial improvement of the flame retardancy, reflected by the decreased values of the heat release rate (HRR_MAX) and total heat release parameter (THR) of the EN composites in comparison to a neat sample (unfilled EN).

SUBMITTER: Marzec A

PROVIDER: S-EPMC6515457 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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New Organic/Inorganic Pigments Based on Azo Dye and Aluminum-Magnesium Hydroxycarbonates with Various Mg/Al Ratios.

Marzec Anna A Szadkowski Bolesław B Rogowski Jacek J Maniukiewicz Waldemar W Rybiński Przemysław P Prochoń Mirosława M

Materials (Basel, Switzerland) 20190425 8

This study set out to investigate the impact of aluminum-magnesium hydroxycarbonates (LHs) with various Mg/Al ratios on the formation of hybrid pigments. The colorants were also evaluated for their flame-retardant properties. In the first part of the study, the hybrid pigments were submitted to comprehensive characterization using time-of-flight secondary ion mass spectrometry (TOF-SIMS), <sup>27</sup>Al solid-state nuclear magnetic resonance (NMR) spectroscopy, powder X-ray diffraction analysis ...[more]

PMID: 31027185

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Project description:Al-Mg-Si series aluminum alloy is a heat-treatment-strengthened alloy. Research on the impact resistance of Al-Mg-Si series aluminum alloy is of great significance to expand its application in engineering. Taking 6082-T6 aluminum alloy as the concrete research object, using the split Hopkinson pressure bar (SHPB) device, the dynamic mechanical response of the material under different temperatures and average strain rates was studied, and the service performance of the material under extreme conditions was determined. The absolute temperature rise was introduced to optimize the existing constitutive model. The results show that when the environment temperature is 298.15~473.15 K under high-speed impact, the internal thermal softening effect of the material is dominant in the competition with the work hardening, resulting in a decrease in the flow stress of the material. Through the analysis of the real stress-strain curve, it was found that the elastic modulus of the material was negatively correlated with the strain rate, negatively correlated with the temperature, and showed an obvious temperature-softening effect. Yield strength was negatively correlated with temperature and positively correlated with strain rate, which showed an obvious strain rate hardening effect. Based on SEM microscopic analysis, it was found that under given conditions, adiabatic shear bands appeared in some samples, and their internal structures demonstrated obvious change. It was judged that when high-speed impact occurs, cracks are induced at the shear bands, and the cracks will continue to develop along the adiabatic shear bands, resulting in many oblique cracks which will gradually become larger and eventually lead to material failure. Finally, based on the model, the strain rate and temperature softening terms were improved, and a rise in adiabatic temperature rise was introduced. The improved model can better describe the strain rate effect of the material and accurately describe its flow stress. It provides a theoretical basis for the engineering application of materials.

Dataset Information

New Organic/Inorganic Pigments Based on Azo Dye and Aluminum-Magnesium Hydroxycarbonates with Various Mg/Al Ratios.

Publications

New Organic/Inorganic Pigments Based on Azo Dye and Aluminum-Magnesium Hydroxycarbonates with Various Mg/Al Ratios.

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