Dataset Information

Basic Blue Dye Adsorption from Water using Polyaniline/Magnetite(Fe₃O₄) Composites: Kinetic and Thermodynamic Aspects.

ABSTRACT: Owing to its exciting physicochemical properties and doping-dedoping chemistry, polyaniline (PANI) has emerged as a potential adsorbent for removal of dyes and heavy metals from aqueous solution. Herein, we report on the synthesis of PANI composites with magnetic oxide (Fe₃O₄) for efficient removal of Basic Blue 3 (BB3) dye from aqueous solution. PANI, Fe₃O₄, and their composites were characterized with several techniques and subsequently applied for adsorption of BB3. Effect of contact time, initial concentration of dye, pH, and ionic strength on adsorption behavior were systematically investigated. The data obtained were fitted into Langmuir, Frundlich, Dubbanin-Rudiskavich (D-R), and Tempkin adsorption isotherm models for evaluation of adsorption parameters. Langmuir isotherm fits closely to the adsorption data with R² values of 0.9788, 0.9849, and 0.9985 for Fe₃O₄, PANI, and PANI/Fe₃O₄ composites, respectively. The maximum amount of dye adsorbed was 7.474, 47.977, and 78.13 mg/g for Fe₃O₄, PANI, and PANI/Fe₃O₄ composites, respectively. The enhanced adsorption capability of the composites is attributed to increase in surface area and pore volume of the hybrid materials. The adsorption followed pseudo second order kinetics with R² values of 0.873, 0.979, and 0.999 for Fe₃O₄, PANI, and PANI/Fe₃O₄ composites, respectively. The activation energy, enthalpy, Gibbs free energy changes, and entropy changes were found to be 11.14, -32.84, -04.05, and -0.095 kJ/mol for Fe₃O₄, 11.97, -62.93, -07.78, and -0.18 kJ/mol for PANI and 09.94, -74.26, -10.63, and -0.210 kJ/mol for PANI/Fe₃O₄ respectively, which indicate the spontaneous and exothermic nature of the adsorption process.

SUBMITTER: Muhammad A

PROVIDER: S-EPMC6600751 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Basic Blue Dye Adsorption from Water using Polyaniline/Magnetite(Fe3O4) Composites: Kinetic and Thermodynamic Aspects.

Muhammad Amir A Shah Anwar-Ul-Haq Ali AA Bilal Salma S Rahman Gul G

Materials (Basel, Switzerland) 20190530 11

Owing to its exciting physicochemical properties and doping-dedoping chemistry, polyaniline (PANI) has emerged as a potential adsorbent for removal of dyes and heavy metals from aqueous solution. Herein, we report on the synthesis of PANI composites with magnetic oxide (Fe3O4) for efficient removal of Basic Blue 3 (BB3) dye from aqueous solution. PANI, Fe3O4, and their composites were characterized with several techniques and subsequently applied for a ...[more]

PMID: 31151258

Similar Datasets

Project description:Conducting polymers (CPs), especially polyaniline (PANI) based hybrid materials have emerged as very interesting materials for the adsorption of heavy metals and dyes from an aqueous environment due to their electrical transport properties, fascinating doping/de-doping chemistry and porous surface texture. Acid Blue 40 (AB40) is one of the common dyes present in the industrial effluents. We have performed a comparative study on the removal of AB40 from water through the application of PANI, magnetic oxide (Fe3O4) and their composites. Prior to this study, PANI and its composites with magnetic oxide were synthesized through our previously reported chemical oxidative synthesis route. The adsorption of AB40 on the synthesized materials was investigated with UV-Vis spectroscopy and resulting data were analyzed by fitting into Tempkin, Freundlich, Dubinin-Radushkevich (D-R) and Langmuir isotherm models. The Freundlich isotherm model fits more closely to the adsorptions data with R2 values of 0.933, 0.971 and 0.941 for Fe3O4, PANI and composites, respectively. The maximum adsorption capacity of Fe3O4, PANI and composites was, respectively, 130.5, 264.9 and 216.9 mg g-1. Comparatively good adsorption capability of PANI in the present case is attributed to electrostatic interactions and a greater number of H-bonding. Effect of pH of solution, temperature, initial concentration of AB40, contact time, ionic strength and dose of adsorbent were also investigated. Adsorption followed pseudo-second-order kinetics. The activation energy of adsorption of AB40 on Fe3O4, PANI and composites were 30.12, 22.09 and 26.13 kJmol-1 respectively. Enthalpy change, entropy change and Gibbs free energy changes are -6.077, -0.026 and -11.93 kJ mol-1 for adsorption of AB40 on Fe3O4. These values are -8.993, -0.032 and -19.87 kJ mol-1 for PANI and -10.62, -0.054 and -19.75 kJ mol-1 for adsorption of AB40 on PANI/Fe3O4 composites. The negative sign of entropy, enthalpy and Gibbs free energy changes indicate spontaneous and exothermic nature of adsorption.

Dataset Information

Basic Blue Dye Adsorption from Water using Polyaniline/Magnetite(Fe₃O₄) Composites: Kinetic and Thermodynamic Aspects.

Publications

Basic Blue Dye Adsorption from Water using Polyaniline/Magnetite(Fe<sub>3</sub>O<sub>4</sub>) Composites: Kinetic and Thermodynamic Aspects.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets