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Enantioselective Diels-Alder reaction of anthracene by chiral tritylium catalysis.

ABSTRACT: The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels-Alder reaction of anthracene.

SUBMITTER: Zhang Q 

PROVIDER: S-EPMC6604712 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature

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Enantioselective Diels-Alder reaction of anthracene by chiral tritylium catalysis.

Zhang Qichao Q   Lv Jian J   Luo Sanzhong S  

Beilstein journal of organic chemistry 20190614

The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels-Alder reaction of anthracene. ...[more]

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