Synthesis and Thermoelectric Properties of Selenium Nanoparticles Coated with PEDOT:PSS.
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ABSTRACT:
SUBMITTER: Kim C
PROVIDER: S-EPMC6631964 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:UnlabelledThe thermoelectric properties of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PedotPSS) and tellurium-PedotPSS (Te-PedotPSS) hybrid composites were enhanced via simple chemical treatment. The performance of thermoelectric materials is determined by their electrical conductivity, thermal conductivity, and Seebeck coefficient. Significant enhancement of the electrical conductivity ofPedotPSS and Te-PedotPSS hybrid composites from 787.99 and 11.01 to 4839.92 and 334.68 S cm(-1), respectively was achieved by simple chemical treatment with H2SO4. The power factor of the developed materials could be effectively tuned over a very wide range depending on the concentration of the H2SO4 solution used in the chemical treatment. The power factors of the developed thermoelectric materials were optimized to 51.85 and 284 ?W m(-1) K(-2), respectively, which represent an increase of four orders of magnitude relative to the corresponding parameters of the untreated thermoelectric materials. Using the Te-PedotPSS hybrid composites, a flexible thermoelectric generator that could be embedded in textiles was fabricated by a printing process. This thermoelectric array generates a thermoelectric voltage of 2 mV using human body heat.
| S-EPMC4700464 | biostudies-literature
Project description:Flexible poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/polypyrrole/paper (PEDOT:PSS/PPy/paper) thermoelectric (TE) nanocomposite films were prepared by a two-step method: first, PPy/paper nanocomposite films were prepared by an in situ chemical polymerization process, and second, PEDOT:PSS/PPy/paper TE composite films were fabricated by coating the as-prepared PPy/paper nanocomposite films using a dimethyl sulfoxide-doped PEDOT:PSS solution. Both the electrical conductivity and the Seebeck coefficient of the PEDOT:PSS/PPy/paper TE nanocomposite films were greatly enhanced from 0.06 S/cm to ~0.365 S/cm, and from 5.44 μV/K to ~16.0 μV/K at ~300 K, respectively, when compared to the PPy/paper TE nanocomposite films. The thermal conductivity of the PEDOT:PSS/PPy/paper composite film (0.1522 Wm-1K-1 at ~300 K) was, however, only slightly higher than that of the PPy/paper composite film (0.1142 Wm-1K-1 at ~300 K). As a result, the ZT value of the PEDOT:PSS/PPy/paper composite film (~1.85 × 10-5 at ~300 K) was significantly enhanced when compared to that of the PPy/paper composite film (~4.73 × 10-7 at ~300 K). The as-prepared nanocomposite films have great potential for application in flexible TE devices.
| S-EPMC5551823 | biostudies-other
Project description:The combination of organic and inorganic materials has been considered an effective solution for achieving ambient thermoelectric energy harvesting and has been developing rapidly. Here, PEDOT:PSS/MWCNT (PPM) composite hydrogels were synthesized using the self-assembled gelation process of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) and the interaction between PEDOT:PSS and multi-walled carbon nanotubes (MWCNTs) without the addition of any surfactant. After immersion in dimethyl sulfoxide and freeze-drying, the hydrogel is easily dispersed in water and used as a direct ink writing (DIW) 3D printing ink. At room temperature, the PPM-20 printed film with 20 wt% MWCNT solids achieved a maximum power factor of 7.37 μW m-1 K-2 and maintained stable thermoelectric properties during repeated bending cycles. On this basis, a thermoelectric generator (TEG) consisting of five legs was printed, which could be produced to generate an open circuit voltage of 6.4 mV and a maximum output power of 40.48 nW at a temperature gradient of 50 K, confirming its great potential for application in high-performance flexible organic/inorganic thermoelectric materials.
| S-EPMC10534393 | biostudies-literature
Project description:Organic materials have attracted attention for thermoelectric
| S-EPMC9476199 | biostudies-literature
Project description:Bioelectricity drives several processes in the human body. The development of new materials that can deliver electrical stimuli is gaining increasing attention in the field of tissue engineering. In this work, novel, highly electrically conductive nanofibers made of poly [2,2'-m-(phenylene)-5,5'-bibenzimidazole] (PBI) have been manufactured by electrospinning and then coated with cross-linked poly (3,4-ethylenedioxythiophene) doped with poly (styrene sulfonic acid) (PEDOT:PSS) by spin coating or dip coating. These scaffolds have been characterized by scanning electron microscopy (SEM) imaging and attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy. The electrical conductivity was measured by the four-probe method at values of 28.3 S·m-1 for spin coated fibers and 147 S·m-1 for dip coated samples, which correspond, respectively, to an increase of about 105 and 106 times in relation to the electrical conductivity of PBI fibers. Human bone marrow-derived mesenchymal stromal cells (hBM-MSCs) cultured on the produced scaffolds for one week showed high viability, typical morphology and proliferative capacity, as demonstrated by calcein fluorescence staining, 4',6-diamidino-2-phenylindole (DAPI)/Phalloidin staining and MTT [3-(4,5-dimethylthiazol-2-yl)-2,5 diphenyl tetrazolium bromide] assay. Therefore, all fiber samples demonstrated biocompatibility. Overall, our findings highlight the great potential of PEDOT:PSS-coated PBI electrospun scaffolds for a wide variety of biomedical applications, including their use as reliable in vitro models to study pathologies and the development of strategies for the regeneration of electroactive tissues or in the design of new electrodes for in vivo electrical stimulation protocols.
| S-EPMC8401200 | biostudies-literature
Project description:Flexible Ag2Se NW/PEDOT:PSS thermoelectric composite films with different Ag2Se contents (10, 20, 30, 50, 70, and 80 wt.%) are fabricated. The Ag2Se nanowires are first fabricated with solution mixing. After that, Ag2Se NW/PEDOT:PSS composite film was fabricated using a simple drop-casting method. To evaluate the potential applications of the Ag2Se NW/PEDOT:PSS composite, their thermoelectric properties are analyzed according to their Ag2Se contents, and strategies for maximizing the thermoelectric power factor are discussed. The maximum room-temperature power factor of composite film (178.59 μW/m·K2) is obtained with 80 wt.% Ag2Se nanowires. In addition, the composite film shows outstanding durability after 1000 repeat bending cycles. This work provides an important strategy for the fabrication of high-performance flexible thermoelectric composite films, which can be extended to other inorganic/organic composites and will certainly promote their development and thermoelectric applications.
| S-EPMC7764283 | biostudies-literature
Project description:The typical conductive polymer of PEDOT:PSS has recently attracted intensive attention in thermoelectric conversion because of its low cost and low thermal conductivity as well as high electrical conductivity. However, compared to inorganic counterparts, the relatively poor thermoelectric performance of PEDOT:PSS has greatly limited its development and high-tech applications. Here, we report a dramatic enhancement in the thermoelectric performance of PEDOT:PSS by constructing unique composite films with graphene quantum dots (GQDs). At room temperature, the electrical conductivity and Seebeck coefficient of PEDOT:PSS/GQDs reached to 7172 S/m and 14.6 μV/K, respectively, which are 30.99% and 113.2% higher than those of pristine PEDOT:PSS. As a result, the power factor of the optimized PEDOT:PSS/GQDs composite is 550% higher than that of pristine PEDOT:PSS. These significant improvements are attributed to the ordered alignment of PEDOT chains on the surface of GQDs, originated from the strong interfacial interaction between PEDOT:PSS and GQDs and the separation of PEDOT and PSS phases. This study evidently provides a promising route for PEDOT:PSS applied in high-efficiency thermoelectric conversion.
| S-EPMC5915444 | biostudies-literature
Project description:Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is one of the most popular conducting polymers and widely used as polymer thermoelectric materials, and its thermoelectric performance could be improved by a variety of post-treatment processes. This paper reported two series of post-treatment methods to enhance the thermoelectric performance. The first series method included pre-treatment of PEDOT:PSS film with formamide, followed by imidazolium-based ionic liquids. The second series method included pre-treatment of PEDOT:PSS film with formamide, followed by sodium formaldehyde sulfoxylate, and finally imidazolium-based ionic liquids. Two series of post-treatment methods significantly improved the power factor of PEDOT:PSS when compared to that of PEDOT:PSS treated with formamide only. For example, using the first series post-treatment method with 40 vol.% ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) amide, the Seebeck coefficient of the PEDOT:PSS film increased from 14.9 to 28.5 μV/K although the electrical conductivity reduced from 2,873 to 1,701 S/cm, resulting in a substantial improvement in the overall power factor from 63.6 to 137.8 μW/K2m. The electrical conductivity enhancement in the formamide-treatment process was in part ascribed to the removal of the insulating PSS component. Further treatment of PEDOT:PSS film with ionic liquid caused dedoping of PEDOT and hence increased in Seebeck coefficient. In contrast, second series post-treatment method led to the reduction in electrical conductivity from 2,873 to 641 S/cm but a big improvement in the Seebeck coefficient from 14.9 to 61.1 μV/K and thus the overall power factor reached up to ~239.2 μW/K2m. Apart from the improvement in electrical conductivity, the increase in Seebeck coefficient is on account of the substantial dedoping of PEDOT polymer to its neutral form and thus leads to the big improvement of its Seebeck coefficient. The environmental stability of ionic liquid-treated PEDOT:PSS films were examined. It was found that the ionic liquid treated PEDOT:PSS retained more than 70% Seebeck coefficient and electrical conductivity at 75% RH humidity and 70°C for 480 h. The improved long-term TE stability is attributed to the strong ionic interaction between sulfonate anions and bulky imidazolium cations that effectively block the penetration of water and lessen the tendency to take up water from the air.
| S-EPMC6960405 | biostudies-literature
Project description:In this study, flexible thermoelectric tin selenide (SnSe)/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) composite films have been fabricated by the vacuum filtration method, and their thermoelectric properties were investigated. The electrical conductivities of the composite films have a tendency to decrease with an increase in the SnSe content, while their Seebeck coefficients have an inverse tendency. The electrical conductivities decrease gradually with an increase in temperature, while the Seebeck coefficients show a tendency to increase first and then decrease with the increase in temperature. The maximum power factor (PF = S 2 σ) of the composite film is obtained when the SnSe content is 10 wt%, which is 24.42 μW m-1 K-2 at 353 K. Besides, the 10 wt% SnSe/PEDOT:PSS film exhibited excellent stability with only a 9% increase in resistance after 1000 bends under a bending radius of 4 mm. When the temperature gradient is 50 K, a flexible thermoelectric generator fabricated by 3 legs of the 10 wt% SnSe/PEDOT:PSS film has an open-circuit voltage and maximum output electrical power of 3.2 mV and 13.73 nW, respectively, which demonstrates a great potential application to power wearable flexible electronic devices.
| S-EPMC9058327 | biostudies-literature
Project description:We present a simple thermoelectric device that consists of a conductive poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)-based inorganic/organic thermoelectric film with high thermoelectric performance. The PEDOT:PSS-coated Se NWs were first chemically synthesized in situ, and then mixed with an Ag precursor solution to produce the PEDOT:PSS-coated Ag2Se NWs. The PEDOT:PSS matrix was then treated with dimethyl sulfoxide (DMSO) prior to the production of flexible PEDOT:PSS-coated Ag2Se NW/PEDOT:PSS composite films with various weight fractions of Ag2Se via a simple drop-casting method. The thermoelectric properties (Seebeck coefficient, electrical conductivity, and power factor) of the composite films were then analyzed. The composite film with 50 wt.% NWs exhibited the highest power factor of 327.15 μW/m·K2 at room temperature. The excellent flexibility of this composite film was verified by bending tests, in which the thermoelectric properties were reduced by only ~5.9% after 1000 bending cycles. Finally, a simple thermoelectric device consisting of five strips of the proposed composite film was constructed and was shown to generate a voltage of 7.6 mV when the temperature difference was 20 K. Thus, the present study demonstrates that that the combination of a chalcogenide and a conductive composite film can produce a high-performance flexible thermoelectric composite film.
| S-EPMC7826913 | biostudies-literature