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Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates.


ABSTRACT: A new bambusuril derivative, (H)BU[6], lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6]. (H)BU[6] is attractive for use as a starting compound for the preparation of other bambusuril derivatives, which was demonstrated via propargylation and the copper-catalyzed click reaction performed on the macrocycle.

SUBMITTER: Havel V 

PROVIDER: S-EPMC6641224 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

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Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates.

Havel Václav V   Sadilová Tereza T   Šindelář Vladimír V  

ACS omega 20180427 4


A new bambusuril derivative, <b>(H)BU[6]</b>, lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril <b>(PMB)BU[6]</b>. <b>(H)BU[6]</b> is attractive for use as a starting compound for the preparation of other bambusuril derivatives, which was demonstrated via propargylation and the copper-catalyzed click reaction performed on the macrocycle. ...[more]

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