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Interfacial Modification of Photoanode|Electrolyte Interface Using Oleic Acid Enhancing the Efficiency of Dye-Sensitized Solar Cells.

ABSTRACT: Dye-sensitized solar cells (DSSCs) are useful devices in converting renewable solar energy into electrical energy. In DSSCs, the triiodide reduction at the surface of TiO₂ is one of the detrimental processes that limit the realization of high efficiencies of the device. To alleviate the active sites available on the semiconductor surface for this detrimental process, the interfacial modification of the dye-adsorbed TiO₂|electrolyte interface has been attempted by coadsorption of oleic acid (OA) over the TiO₂ surface. Thus, the modified cell exhibited a higher efficiency (η) of 12.9% under one sun illumination when compared with that of the unmodified cell (η = 11.1%). To provide an insight into the OA anchoring and dynamics of electron transport at the photoanode|electrolyte interface, molecular spectroscopic and electrochemical impedance spectroscopic analyses were carried out. A red shift in the optical absorption spectrum was observed after the addition of OA to dye-adsorbed TiO₂. The binding of OA to TiO₂ surface was found to be through bridging bidentate type. Mott-Schottky analyses of the DSSCs under dark conditions were made to probe the shift in the Fermi level of TiO₂ upon OA modification. In addition, the Förster resonance energy transfer (FRET) has been found between OA and N719 dye. Thus, the red shift in the optical absorption, enhanced electron-transfer kinetics, and FRET contributes to the observed enhancement in the efficiency of the device containing OA-modified photoanode.

SUBMITTER: Anantharaj G

PROVIDER: S-EPMC6643926 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:The dye-sensitized solar cell (DSSC) is a potential alternative to the widely used Si-based solar cell, with several advantages including higher energy conversion efficiency under weak and indirect illumination conditions, and the possibility of practical application in urban life due to their exterior characteristics. However, despite these advantages, the energy conversion efficiency of DSSCs has remained low at ∼10%. To improve the efficiency of DSSCs, research has been done on modifying the materials used in DSSC component parts, such as the photoanode, electrolyte, and counter electrode. Another approach is to modify the photoanode to increase the diffusion coefficient, reduce the recombination rate, and enhance the light behavior. One of the most popular methods for improving the efficiency of DSSCs is by trapping and dispersing the incident light using a scattering layer. Use of a scattering layer has shown various and interesting results, depending on the application, but it is currently used only in a simple form and there has been no deep research on the further potential of the scattering layer. In this study, the scattering center was introduced to maximize the effect of scattering. Light distribution near the scattering center, within or on the photoanode, was investigated using finite differential time domain (FDTD) numerical methods. Based on the FDTD analysis, an optimized, dome-shaped three-dimensional modified structure of a transparent photoanode with minimized scattering centers was introduced and indicated the possibility of modifying the photon distribution in the photoanode to enhance the performance of DSSCs. In addition to using the scattering center, we have introduced the structure of the dome-shaped three-dimensional structure to utilize the light distribution within the photoanode. This novel three-dimensional transparent photoanode and scattering center design increased the energy conversion efficiency of DSSCs from 6.3 to 7.2%. These results provide a foundation for investigating the role of the scattering center via further in-depth research. This new three-dimensional photoanode design provides a means to overcome the previous limitations on DSSC performance.

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Interfacial Modification of Photoanode|Electrolyte Interface Using Oleic Acid Enhancing the Efficiency of Dye-Sensitized Solar Cells.

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