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Catalytic Conversion of Biomass-Derived 1,2-Propanediol to Propylene Oxide over Supported Solid-Base Catalysts.

ABSTRACT: A series of supported alkali metal salts were investigated as catalysts to produce propylene oxide (PO) from biomass-derived 1,2-propanediol via dehydrative epoxidation in a solid-gas reaction system. The effects of supports, cations, and anions in the alkali metal salts and calcination temperature were investigated by X-ray diffraction and CO2-temperature-programmed desorption. The results indicate the catalysts with relative mild basicity having higher yields of PO. The highest yield of PO is 58.2% from reactions at 400 °C at an atmospheric pressure over KNO3/SiO2. In addition, the catalyst could be reused after calcination in air at 550 °C.

SUBMITTER: Liu C 

PROVIDER: S-EPMC6644628 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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Catalytic Conversion of Biomass-Derived 1,2-Propanediol to Propylene Oxide over Supported Solid-Base Catalysts.

Liu Chengyun C   Xin Junna J   Tan Jihuai J   Liu Tuan T   Kessler Michael R MR   Zhang Jinwen J  

ACS omega 20180807 8

A series of supported alkali metal salts were investigated as catalysts to produce propylene oxide (PO) from biomass-derived 1,2-propanediol via dehydrative epoxidation in a solid-gas reaction system. The effects of supports, cations, and anions in the alkali metal salts and calcination temperature were investigated by X-ray diffraction and CO<sub>2</sub>-temperature-programmed desorption. The results indicate the catalysts with relative mild basicity having higher yields of PO. The highest yiel  ...[more]

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