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Enhanced Photocatalytic Efficiency of a Least Active Ag-TiO₂ by Amine Adsorption.

ABSTRACT: An Ag-TiO₂ photocatalyst with 3.5 atom % silver content, synthesized by a single step sol-gel method, possessed silver nanoparticles (AgNPs; 1-5 nm) on the TiO₂ surface, but owing to the nonplasmonic nature of AgNPs and the wide band gap of TiO₂, this material exhibited poor activity in a photocatalytic degradation reaction. However, this least active Ag-TiO₂ catalyst showed a sudden increase in activity during a photocatalytic amine self-coupling reaction showing the highest activity, which was interpreted as amine (reactant) adsorption-driven activity enhancement. We found that amine adsorption occurred over AgNPs converting into plasmonic AgNPs as well as on the TiO₂ surface reducing the band gap and therefore facilitated the visible light excitation and the electron-transfer process efficiently, resulting into overall enhancement in the photocatalytic activity. Thus, a very efficient, stable, and visible light active photocatalyst (amine-adsorbed Ag-TiO₂) was developed by simply adsorbing an amine in the least active Ag-TiO₂ photocatalyst.

SUBMITTER: Mogal SI

PROVIDER: S-EPMC6644989 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature

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Enhanced Photocatalytic Efficiency of a Least Active Ag-TiO2 by Amine Adsorption.

Mogal Sajid Ismailkhan SI Shah Dinesh Ochhavlal DO Mukherjee Tulsi T Shripathi Thoudinja T Mishra Manish Kumar MK

ACS omega 20181008 10

An Ag-TiO2 photocatalyst with 3.5 atom % silver content, synthesized by a single step sol-gel method, possessed silver nanoparticles (AgNPs; 1-5 nm) on the TiO2 surface, but owing to the nonplasmonic nature of AgNPs and the wide band gap of TiO2, this material exhibited poor activity in a photocatalytic degradation reaction. However, this least active Ag-TiO2 catalyst showed a sudden increase in activity during a photocatalytic amine self-coupling reac ...[more]

PMID: 31458006

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Project description:TiO2 nanofibers were fabricated by combination of sol-gel and electrospinning techniques. Ag-doped TiO2 nanofibers with different Ag contents were prepared by two different methods (in situ electrospinning or wetness impregnation of Ag on TiO2 nanofibers) and heat treated at 500 °C for 2 h under an air or N2 atmosphere. The obtained catalysts were characterized by field emission scanning electron microscopy, X-ray diffraction, photoluminescence, and N2 adsorption analyzed by the Brunauer-Emmett-Teller (BET) method. Photocatalytic glucose conversions with electrospun TiO2 and Ag-doped TiO2 nanofibers for production of high-value products were carried out. From different doping methods, the results indicated that 1 wt % Ag-TiO2 nanofibers prepared by an in situ method with calcination under N2 achieved the highest glucose conversion (85.49%). From several Ag loading contents (i.e., 0, 1, 2, and 4 wt %) in Ag-doped TiO2 nanofibers, the nanofibers exhibited different glucose conversions [in order of 2 wt % (99.65%) > 1 wt % (85.49%) > 4 wt % (77.72%) > 0 wt % (29.64%)]. Arabinose, xylitol, gluconic acid, and formic acid were found as the high-value chemicals with the photocatalytic reaction of TiO2 and Ag-doped TiO2 nanofibers under UVA irradiation. Product yields of each converted chemicals from different photocatalysts from different Ag loading contents showed relatively same trends with the glucose conversion. From all results, it can be concluded that the good characteristics of 2 wt % Ag-TiO2 nanofibers such as the smallest anatase crystallite size (8.25 nm) and the highest specific surface area (S BET = 53.69 m2/g) promoted the highest photocatalytic activity. Additionally, TiO2 and Ag-doped TiO2 nanofibers exhibited higher photocatalytic performance for glucose conversion than commercial TiO2 (P25) and synthesized TiO2 nanoparticles. Finally, Ag-doped TiO2 nanofibers showed recycling ability with high photocatalytic glucose conversion after four-time use.

Dataset Information

Enhanced Photocatalytic Efficiency of a Least Active Ag-TiO₂ by Amine Adsorption.

Publications

Enhanced Photocatalytic Efficiency of a Least Active Ag-TiO<sub>2</sub> by Amine Adsorption.

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