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Synthesis of ZSM-5/Siliceous Zeolite Composites for Improvement of Hydrophobic Adsorption of Volatile Organic Compounds.


ABSTRACT: In this research, we investigated the hydrophobicity and dynamic adsorption-desorption behaviors of volatile organic compounds (VOCs) by applying different optimized coating dosage (25, 50, and 75%) on designed novel ZSM-5/MCM-41 and ZSM-5/Silicalite-1 hierarchical composites. The relatively large specific surface area and pore volume of adsorbents ZSM-5/MCM-41 and ZSM-5/Silicalite-1 composites with excellent stability were affirmed by ex-situ XRD, FTIR, BET, SEM, and water contact angle analyses. Regarding, toluene adsorption-desorption investigation, ZSM-5/MCM-41 composite lead a longer stable toluene breakthrough time no matter under dry or 50% humid conditions. However, under different loading dosage condition, the breakthrough time of 75% coating ratio was the longest, which was 1.6 times as long as that of pure ZSM-5 under wet adsorption. Meanwhile, the complete elimination of toluene for ZSM-5/MCM-41-75% was done by largest desorption peak area and the lowest desorption temperature of 101.9°C, while, the largest contact angle of ZSM-5/MCM-41-75% was 17.0° higher than pure ZSM-5 zeolite. Therefore, we believe that the present hydrophobic sorbent will provide new insight with great research potential for removing low concentration of VOCs at industrial scale.

SUBMITTER: Li R 

PROVIDER: S-EPMC6647869 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature

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Synthesis of ZSM-5/Siliceous Zeolite Composites for Improvement of Hydrophobic Adsorption of Volatile Organic Compounds.

Li Renna R   Chong Shijia S   Altaf Naveed N   Gao Yanshan Y   Louis Benoit B   Wang Qiang Q  

Frontiers in chemistry 20190716


In this research, we investigated the hydrophobicity and dynamic adsorption-desorption behaviors of volatile organic compounds (VOCs) by applying different optimized coating dosage (25, 50, and 75%) on designed novel ZSM-5/MCM-41 and ZSM-5/Silicalite-1 hierarchical composites. The relatively large specific surface area and pore volume of adsorbents ZSM-5/MCM-41 and ZSM-5/Silicalite-1 composites with excellent stability were affirmed by <i>ex-situ</i> XRD, FTIR, BET, SEM, and water contact angle  ...[more]

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