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Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association.

ABSTRACT: A mild and efficient amination of arenes with azodicarboxylates using potassium bisulfate (KHSO4) as the catalyst in 1,1,1,3,3,3-hexafluoro-2-propanol has been developed. This protocol allowed the amination of a broad range of arenes leading to corresponding hydrazides in good to excellent yields.

SUBMITTER: Tang RJ 

PROVIDER: S-EPMC6648143 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association.

Tang Ren-Jin RJ   Retailleau Pascal P   Milcent Thierry T   Crousse Benoit B  

ACS omega 20190522 5

A mild and efficient amination of arenes with azodicarboxylates using potassium bisulfate (KHSO<sub>4</sub>) as the catalyst in 1,1,1,3,3,3-hexafluoro-2-propanol has been developed. This protocol allowed the amination of a broad range of arenes leading to corresponding hydrazides in good to excellent yields. ...[more]

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