Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Graphite Whiskers Derived from Waste Coffee Grounds Treated at High Temperature.

ABSTRACT: Graphite whiskers (GWs) are obtained from coffee grounds (CGs) treated at 2500 °C for 1 h in the presence of Ar gas at 1 atm. The majority of the GWs formed inside the CGs shell are rod-like with a conical tip with diameter and length in the range between 1 to 3 µm and 4 to 10 µm, respectively. At first, the carbon layer might be grown in a turbostratic manner, and then progressively graphitized at higher temperature. The strong G' peak intensity might be induced by the disclination of graphitized carbon layers.

SUBMITTER: Melvin GJH

PROVIDER: S-EPMC6686167 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Graphite Whiskers Derived from Waste Coffee Grounds Treated at High Temperature.

Melvin Gan Jet Hong GJH Wang Zhipeng Z Morimoto Shingo S Fujishige Masatsugu M Takeuchi Kenji K Hashimoto Yoshio Y Endo Morinobu M

Global challenges (Hoboken, NJ) 20190212 8

Graphite whiskers (GWs) are obtained from coffee grounds (CGs) treated at 2500 °C for 1 h in the presence of Ar gas at 1 atm. The majority of the GWs formed inside the CGs shell are rod-like with a conical tip with diameter and length in the range between 1 to 3 µm and 4 to 10 µm, respectively. At first, the carbon layer might be grown in a turbostratic manner, and then progressively graphitized at higher temperature. The strong G' peak intensity might be induced by the disclination of graphitiz ...[more]

PMID: 31565389

Similar Datasets

Biochar of Spent Coffee Grounds as Per Se and Impregnated with TiO2: Promising Waste-Derived Adsorbents for Balofloxacin.

Project description:Biochars (BC) of spent coffee grounds, both pristine (SCBC) and impregnated with titanium oxide (TiO2@SCBC) were exploited as environmentally friendly and economical sorbents for the fluroquinolone antibiotic balofloxacin (BALX). Surface morphology, functional moieties, and thermal stabilities of both adsorbents were scrutinized using SEM, EDS, TEM, BET, FTIR, Raman, and TG/dT analyses. BET analysis indicated that the impregnation with TiO2 has increased the surface area (50.54 m2/g) and decreased the pore size and volume. Batch adsorption experiments were completed in lights of the experimental set-up of Plackett-Burman design (PBD). Two responses were maximized; the % removal (%R) and the adsorption capacity (qe, mg/g) as a function of four variables: pH, adsorbent dosage (AD), BALX concentration ([BALX]), and contact time (CT). %R of 68.34% and 91.78% were accomplished using the pristine and TiO2@SCBC, respectively. Equilibrium isotherms indicated that Freundlich model was of a perfect fit for adsorption of BALX onto both adsorbents. Maximum adsorption capacity (qmax) of 142.55 mg/g for SCBC and 196.73 mg/g for the TiO2@SCBC. Kinetics of the adsorption process were best demonstrated using the pseudo-second order (PSO) model. The adsorption-desorption studies showed that both adsorbents could be restored with the adsorption efficiency being conserved up to 66.32% after the fifth cycles.

| S-EPMC8071459 | biostudies-literature

Coffee Grounds-Derived CNPs for Efficient Cr(VI) Water Remediation.

Project description:Carbon nanomaterials are a group of materials characterized by sp2/sp3 carbon backbone which, combined with surface atoms and/or chemical groups, ensures peculiar physical chemical features for a wide range of applications. Among these materials, carbon dots and carbon nanoparticles belong to carbon nanomaterials with a few nanometer dimensions. In this work, carbon nanoparticles were produced from spent coffee grounds as sustainable carbon source through a simple, cheap and eco-friendly procedure according to an oxidation process (at controlled temperature) driven by hydrogen peroxide. Atomic Force Microscope (AFM) and fluorescence, UV-Vis absorption, FT-IR and Raman spectroscopy were used to assess the formation of carbon nanomaterials of about 10 nm with the typical emission and absorption properties of carbon dots and peculiar surface features. In fact, the presence of heteroatoms, i.e., phosphorus, and the carbonyl/carboxyl surface groups on carbon nanoparticles, was proposed to confer peculiar properties allowing the fast Mn(VII) reduction to Mn(II) at neutral pH and the Cr(VI) reduction to Cr(III) in weak acid aqueous media.

| S-EPMC8143114 | biostudies-literature

Coffee waste

Project description:Hydrogen, alcohols and volatile fatty acids from the co-digestion of coffee waste (coffee pulp, husk, and manufacturing wastewater) by applying autochthonous microorganisms

| PRJEB31208 | ENA

Enhanced methane production with co-feeding spent coffee grounds using spare capacity of existing anaerobic food waste digesters.

Project description:With increasing coffee consumption worldwide, the efficient and sustainable management of spent coffee grounds (SCG) has become increasingly challenging. This study investigated the anaerobic co-digestion of small amounts of SCG with food waste (FW) at increasing co-feeding ratios of 1:100-1:10 (volatile solids basis) to assess the possibility of SCG treatment using the spare capacity of existing anaerobic digesters. Co-feeding SCG increased methane production compared to FW mono-digestion in the tested range of co-feeding ratios without compromising process stability. Methane yield did not further increase when the SCG/FW ratio increased above 4%, and process failure occurred at a 1:10 co-feeding ratio without trace element supplementation. The enhanced methanogenic performance was attributed to increased protein removal efficiency, which was potentially related to the promotion of peptide hydrolysis. The overall results suggest that co-feeding appropriate small amounts of SCG to FW digesters can be a realistic sustainable option for SCG management.

| S-EPMC10891051 | biostudies-literature

Quantifying surface morphology of manufactured activated carbon and the waste coffee grounds using the Getis-Ord-Gi* statistic and Ripley's K function.

Project description:Activated carbon can be manufactured from waste coffee grounds via physical and/or chemical activation processes. However, challenges remain to quantify the differences in surface morphology between manufactured activated carbon granules and the waste coffee grounds. This paper presents a novel quantitative method to determine the quality of the physical and chemical activation processes performed in the presence of intensity inhomogeneity and identify surface characteristics of manufactured activated carbon granules and the waste coffee grounds. The spatial density was calculated by the Getis-Ord-Gi* statistic in scanning electron microscopy images. The spatial characteristics were determined by analyzing Ripley's K function and complete spatial randomness. Results show that the method introduced in this paper is capable of distinguishing between manufactured activated carbon granules and the waste coffee grounds, in terms of surface morphology.

| S-EPMC8024374 | biostudies-literature

High yield conversion of biowaste coffee grounds into hierarchical porous carbon for superior capacitive energy storage.

Project description:Recently great efforts have been focused on converting biowastes into high-valued carbon materials. However, it is still a great challenge to achieve high carbon yield and controllable porous distribution in both industrial and academic research. Inspired by the multi-void structure of waste coffee grounds, herein we fabricated hierarchical porous carbon via the combination of catalytic carbonization and alkali activation. The catalytic carbonization process was applied to obtain well-defined mesoporous carbon with carbon yield as high as 42.5 wt%, and subsequent alkali activation process produced hierarchical porous carbon with ultrahigh specific surface area (3549 m2 g-1) and large meso-/macropores volume (1.64 cm3 g-1). In three-electrode system, the electrode exhibited a high capacitance of 440 F g-1 at 0.5 A g-1 in 6 M KOH aqueous electrolyte, superior to that of many reported biomass-derived porous carbons. In two-electrode system, its energy density reached to 101 Wh kg-1 at the power density of 900 W kg-1 in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate (EMIMBF4). This work provided a cost-effective strategy to recycle biowastes into hierarchical porous carbon with high yield for high-performance energy storage application.

| S-EPMC7044333 | biostudies-literature

Spent Coffee Grounds Alter Bacterial Communities in Latxa Dairy Ewes.

Project description:Antimicrobial and antioxidant properties of spent coffee grounds (SCG) make them a potential ingredient in a diet for ruminants. This study investigated the effects of SCG on rumen microbiota. For 51 days, 36 dairy ewes were assigned to the experimental treatments (0, 30, 50, and 100 g SCG/kg). Ruminal samples were collected on day 50. DNA was extracted and subjected to paired-end Illumina sequencing of the V3-V4 hypervariable region of the 16S rRNA genes. Bioinformatic analyses were performed using QIIME (v.1.9.0). SCG increased dose-dependently bacterial diversity and altered bacterial structure. Further, 60, 78, and 449 operational taxonomic unit (OUT) were different between control and 30, 50 and 100 g/kg SCG groups, respectively. Higher differences were observed between the control and 100 g/kg SCG group, where OTU of the genera Treponema, CF231, Butyrivibrio, BF331, Anaeroplasma, Blautia, Fibrobacter, and Clostridium were enriched with SCG. Correlations between volatile fatty acids (VFA) and bacterial taxa were sparser in the SCG groups and had little overlap. Certain bacterial taxa presented different signs of the correlation with VFA in SCG and control groups, but Butyrivibrio and Blautia consistently correlated with branched-chain VFA in all groups. SCG induced shifts in the ruminal bacterial community and altered the correlation networks among bacterial taxa and ruminal VFA.

| S-EPMC7764017 | biostudies-literature

Spent Coffee Grounds Derived Carbon Loading C, N Doped TiO<sub>2</sub> for Photocatalytic Degradation of Organic Dyes.

Project description:Titanium dioxide (TiO2) is an ideal photocatalyst candidate due to its high activity, low toxicity and cost, and high chemical stability. However, its practical application in photocatalysis is seriously hindered by the wide band gap energy of TiO2 and the prone recombination of electron-hole pairs. In this study, C, N doped TiO2 were supported on spent coffee grounds-derived carbon (ACG) via in situ formation, which was denoted as C, N-TiO2@ACG. The obtained C, N-TiO2@ACG exhibits increased light absorption efficiency with the band gap energy decreasing from 3.31 eV of TiO2 to 2.34 eV, a higher specific surface area of 145.8 m2/g, and reduced recombination rates attributed to the synergistic effect of a spent coffee grounds-derived carbon substrate and C, N doping. Consequently, the optimal 1:1 C, N-TiO2@ACG delivers considerable photocatalytic activity with degradation efficiencies for methylene blue (MB) reaching 96.9% within 45 min, as well as a high reaction rate of 0.06348 min-1, approximately 4.66 times that of TiO2 (0.01361 min-1). Furthermore, it also demonstrated greatly enhanced photocatalytic efficiency towards methyl orange (MO) in the presence of MB compared with a single MO solution. This work provides a feasible and universal strategy of synchronous introducing nonmetal doping and biomass-derived carbon substrates to promote the photocatalytic performance of TiO2 for the degradation of organic dyes.

| S-EPMC10385829 | biostudies-literature

Spent Coffee Grounds as Eco-Friendly Additives for Aluminum-Air Batteries.

Project description:A new approach to the recycling of spent coffee grounds is described in which lignin, a chemical component of spent coffee, is used as an electrolyte additive in aluminum-air batteries. The effect of lignin on the performance of aluminum-air batteries has been investigated by weight loss measurement, galvanostatic discharge test, and electrochemical impedance spectroscopy (EIS). The corrosion inhibition efficiency is improved up to 37.3% and fuel efficiency up to 21.7% at 500 ppm of lignin molecules. The chemisorption of lignin molecules on the aluminum surface improves battery performance. Adsorption of lignin molecules onto the aluminum surface is driven by the electrostatic interaction between the lignin's hydroxyl group and the aluminum surface. The mechanism for the performance improvement is explained by the chemisorption behavior of lignin molecules. The adsorption behavior has been investigated by scanning electronic microscopy with energy-dispersive spectroscopy (SEM-EDS), laser scanning microscopy (LSM), atomic force microscopy (AFM), Freundlich adsorption isotherm, Fourier-transform infrared (FT-IR) spectroscopy, and the computational calculation of adsorption energies based on the density functional theory (DFT).

| S-EPMC8495842 | biostudies-literature

Recycling of spent coffee grounds for useful extracts and green composites.

Project description:Large amounts of spent coffee grounds (SCGs) are often discarded and there is a need to find alternative disposal methods due to environmental concerns. This project aims to develop sustainable materials by re-purposing spent coffee grounds (SCGs). Oil extraction was performed using different organic solvents and yielded approximately 10% coffee oil. Coffee oil contains potentially useful chemical compounds such as fatty acids and caffeine. They also exhibited antioxidant properties. Extracted SCGs (ESCGs) were blended with epoxy resin to form composites. ESCG composites displayed a general decrease in mechanical properties relative to epoxy. However, improvements were observed when comparing ESCG composites and SCG composites. The greatest improvement belongs to epoxy composite filled with acetone-ESCGs, where the tensile strength, flexural modulus and flexural strength increased to 23.4 MPa, 3.02 GPa and 42.9 MPa respectively. This study presents a way to exploit waste materials which contributes to the goal of sustainability.

| S-EPMC8693820 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data