Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Performance and Stability Improvement of Layered NCM Lithium-Ion Batteries at High Voltage by a Microporous Al2O3 Sol-Gel Coating.

ABSTRACT: A simple and low-cost polymer-aided sol-gel method was developed to prepare ?-Al2O3 protective layers for LiNi0.6Co0.2Mn0.2O2 (NCM622) cathode materials. The selected polyvinyl alcohol polymer additive not only facilitates the formation of a uniform and thin ?-Al2O3 layer on the irregular and rough cathode particle surface to protect it from corrosion but also serves as a pore-forming agent to generate micropores in the film after sintering to allow fast transport of lithium ions, which guaranteed the excellent and stable battery performance at high working voltage. Detailed studies in the full battery mode showed that the leached corrosion species from the cathode had a more profound harmful effect to the graphite anode, which seemed to be the dominating factor that caused the battery performance decay.

SUBMITTER: Wu Y

PROVIDER: S-EPMC6714605 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Performance and Stability Improvement of Layered NCM Lithium-Ion Batteries at High Voltage by a Microporous Al2O3 Sol-Gel Coating.

Wu Yingqiang Y Li Mengliu M Wahyudi Wandi W Sheng Guan G Miao Xiaohe X Anthopoulos Thomas D TD Huang Kuo-Wei KW Li Yangxing Y Lai Zhiping Z

ACS omega 20190819 9

A simple and low-cost polymer-aided sol-gel method was developed to prepare γ-Al2O3 protective layers for LiNi0.6Co0.2Mn0.2O2 (NCM622) cathode materials. The selected polyvinyl alcohol polymer additive not only facilitates the formation of a uniform and thin γ-Al2O3 layer on the irregular and rough cathode particle surface to protect it from corrosion but also serves as a pore-forming agent to generate microp ...[more]

PMID: 31497715

Similar Datasets

Dual function Li-reactive coating from residual lithium on Ni-rich NCM cathode material for Lithium-ion batteries.

Project description:In this study, lithium phosphate (Li3PO4) is coated on the surface of Ni-rich LiNi0.91Co0.06Mn0.03O2 cathode material to enhance its cyclability and rate performance. The process is carried-out by achieving dual benefits, reduction of residual lithium compounds by converting them into Li3PO4 coating material. The 0.1 mol.% Li3PO4 (LiP) sample exhibits a capacity retention of 82% while the pristine NCM shows only 68.1% after 100 cycles. In addition, the LiP-0.1 NCM delivers high discharge capacities (161.9 mAh g-1 at 3C, 144.3 mAh g-1 at 4C and 94.6 mAh g-1 at 5C) as compared to the pristine NCM (129.3 mAh g-1 at 3C, 67.4 mAh g-1 at 4C and 33.4 mAh g-1 at 5C) in the voltage range of 3.0-4.3 V. In addition, the irreversible phase transition has also suppressed in the coated sample which is confirmed by cyclic voltammetry. Our study suggests that Li3PO4 coating reduces the polarization and acts as protecting layer between the electrode and electrolyte that results in the superior electrochemical performance.

| S-EPMC8452671 | biostudies-literature

LiNbO3 Thin Films through a Sol-Gel/Spin-Coating Approach Using a Novel Heterobimetallic Lithium-Niobium Precursor.

Project description:Lithium niobate is a lead-free material which has attracted considerable attention due to its excellent optical, piezoelectric, and ferroelectric properties. This research is devoted to the synthesis through an innovative sol-gel/spin-coating approach of polycrystalline LiNbO3 films on Si substrates. A novel single-source hetero-bimetallic precursor containing lithium and niobium was synthesized and applied to the sol-gel synthesis. The structural, compositional, and thermal characteristics of the precursor have been tested through attenuated total reflection, X-ray photoelectron spectroscopy, thermogravimetric analysis, and differential scanning calorimetry. The LiNbO3 films have been characterized from a structural point of view with combined X-ray diffraction and Raman spectroscopy. Field-emission scanning electron microscopy, energy dispersive X-ray analysis, and X-ray photoelectron spectroscopy have been used to study the morphological and compositional properties of the deposited films.

| S-EPMC10892834 | biostudies-literature

Hierarchical Porous and Three-Dimensional MXene/SiO2 Hybrid Aerogel through a Sol-Gel Approach for Lithium-Sulfur Batteries.

Project description:A unique porous material, namely, MXene/SiO2 hybrid aerogel, with a high surface area, was prepared via sol-gel and freeze-drying methods. The hierarchical porous hybrid aerogel possesses a three-dimensional integrated network structure of SiO2 cross-link with two-dimensional MXene; it is used not only as a scaffold to prepare sulfur-based cathode material, but also as an efficient functional separator to block the polysulfides shuttle. MXene/SiO2 hybrid aerogel as sulfur carrier exhibits good electrochemical performance, such as high discharge capacities (1007 mAh g-1 at 0.1 C) and stable cycling performance (823 mA h g-1 over 200 cycles at 0.5 C). Furthermore, the battery assembled with hybrid aerogel-modified separator remains at 623 mA h g-1 over 200 cycles at 0.5 C based on the conductive porous framework and abundant functional groups in hybrid aerogel. This work might provide further impetus to explore other applications of MXene-based composite aerogel.

| S-EPMC9610511 | biostudies-literature

Photocatalytic Degradation of Diclofenac Using Al2O3-Nd2O3 Binary Oxides Prepared by the Sol-Gel Method.

Project description:This paper reports the sol-gel synthesis of Al2O3-Nd2O3 (Al-Nd-x; x = 5%, 10%, 15% and 25% of Nd2O3) binary oxides and the photodegradation of diclofenac activated by UV light. Al-Nd-based catalysts were analyzed by N2 physisorption, XRD, TEM, SEM, UV-Vis and PL spectroscopies. The inclusion of Nd2O3 in the aluminum oxide matrix in the 10-25% range reduced the band gap energies from 3.35 eV for the ?-Al2O3 to values as low as 3.13-3.20 eV, which are typical of semiconductor materials absorbing in the UV region. ?-Al2O3 and Al-Nd-x binary oxides reached more than 92.0% of photoconverted diclofenac after 40 min of reaction. However, the photocatalytic activity in the diclofenac degradation using Al-Nd-x with Nd2O3 contents in the range 10-25% was improved with respect to that of ?-Al2O3 at short reaction times. The diclofenac photoconversion using ?-Al2O3 was 63.0% at 10 min of UV light exposure, whereas Al-Nd-15 binary oxide reached 82.0% at this reaction time. The rate constants determined from the kinetic experiments revealed that the highest activities in the aqueous medium were reached with the catalysts with 15% and 25% of Nd2O3, and these compounds presented the lowest band gap energies. The experimental results also demonstrated that Nd2O3 acts as a separator of charges favoring the decrease in the recombination rate of electron-hole pairs.

| S-EPMC7142804 | biostudies-literature

Stabilizing polymer electrolytes in high-voltage lithium batteries.

Project description:Electrochemical cells that utilize lithium and sodium anodes are under active study for their potential to enable high-energy batteries. Liquid and solid polymer electrolytes based on ether chemistry are among the most promising choices for rechargeable lithium and sodium batteries. However, uncontrolled anionic polymerization of these electrolytes at low anode potentials and oxidative degradation at working potentials of the most interesting cathode chemistries have led to a quite concession in the field that solid-state or flexible batteries based on polymer electrolytes can only be achieved in cells based on low- or moderate-voltage cathodes. Here, we show that cationic chain transfer agents can prevent degradation of ether electrolytes by arresting uncontrolled polymer growth at the anode. We also report that cathode electrolyte interphases composed of preformed anionic polymers and supramolecules provide a fundamental strategy for extending the high voltage stability of ether-based electrolytes to potentials well above conventionally accepted limits.

| S-EPMC6626095 | biostudies-literature

Stable sol-gel hydroxyapatite coating on zirconia dental implant for improved osseointegration.

Project description:Aside from being known for its excellent mechanical properties and aesthetic effect, zirconia has recently attracted attention as a new dental implant material. Many studies have focused on hydroxyapatite (HA) coating for obtaining improved biocompatibility, however the coating stability was reduced by a byproduct produced during the high-temperature sintering process. In this study, to overcome this problem, we simply coated the zirconia surface with a sol-gel-derived hydroxyapatite (HA) layer and then sintered it at a varied temperature (<1000 °C). The surface showed a nanoporous structure, and there was no crystalline phase other than HA and zirconia when the sintering temperature was 800 °C. The adhesion strength of the HA layer (>40 MPa) was also appropriate as a dental implant application. In addition, in vitro cell experiments using a preosteoblast cell line revealed that the HA-coated zirconia surface acts as a preferable surface for cell attachment and proliferation than bare zirconia surface. In vivo animal experiments also demonstrated that the osteoconductivity of zirconia were dramatically enhanced by HA coating, which was comparable to that of Ti implant. These results suggest that the sol-gel-based HA-coated zirconia has a great potential for use as a dental implant material.

| S-EPMC8245356 | biostudies-literature

Optimization of Hybrid Sol-Gel Coating for Dropwise Condensation of Pure Steam.

Project description:We developed hybrid organic-inorganic sol-gel silica coatings with good durability in harsh environment (high temperatures, high vapor velocities) and with slightly hydrophobic behavior, sufficient to promote dropwise condensation (DWC) of pure steam. DWC is a very promising mechanism in new trends of thermal management and power generation systems to enhance the heat transfer during condensation as compared to film-wise condensation (FWC). The sol-gel coatings have been prepared from methyl triethoxy silane (MTES) and tetraethyl-orthosilicate (TEOS) and deposited on an aluminum substrate. The coatings were optimized in terms of precursor ratio and annealing temperature highlighting potentials and limits of such mixtures. A comprehensive surface characterization before and after saturated steam condensation tests has been performed and related to the thermal measurements for evaluating the heat transfer augmentation as compared to FWC obtained on untreated aluminum surfaces. The results showed that the developed hybrid organic-inorganic sol-gel silica coatings are promising DWC promoters.

| S-EPMC7078621 | biostudies-literature

Optimization of Layered Cathode Materials for Lithium-Ion Batteries.

Project description:This review presents a survey of the literature on recent progress in lithium-ion batteries, with the active sub-micron-sized particles of the positive electrode chosen in the family of lamellar compounds LiMO₂, where M stands for a mixture of Ni, Mn, Co elements, and in the family of yLi₂MnO₃•(1 - y)LiNi½Mn½O₂ layered-layered integrated materials. The structural, physical, and chemical properties of these cathode elements are reported and discussed as a function of all the synthesis parameters, which include the choice of the precursors and of the chelating agent, and as a function of the relative concentrations of the M cations and composition y. Their electrochemical properties are also reported and discussed to determine the optimum compositions in order to obtain the best electrochemical performance while maintaining the structural integrity of the electrode lattice during cycling.

| S-EPMC5456936 | biostudies-other

Multi-Functional Luminescent Coating for Wood Fabric Based on Silica Sol-Gel Approach.

Project description:Environmentally friendly protection coatings have obtained increasing attention for their use in wooden materials, which can be destroyed easily when exposed to outdoor environments. A series of silane sol coatings coordinated with Eu3+ was prepared by hydrolyzing silane compounds. The obtained luminescent coating with three-dimensional net structure showed excellent optical, anti-ultraviolet aging, and thermal stability. The hybrid silane-modified compound coating was well-distributed on the wood by Si-O bonds to prevent its removal. The compound coating could stave off the decomposition of wood by converting ultraviolet light into red light and a charring action can endow the wood with thermal stability at high temperature, demonstrating the improvement of fire resistance and radiation residence following prolonged exposure to ultraviolet light, proving its excellent anti-ultraviolet aging properties.

| S-EPMC7795870 | biostudies-literature

Ionic Liquid Functionalized Gel Polymer Electrolytes for Stable Lithium Metal Batteries.

Project description:Metallic lithium (Li) is regarded as the ideal anode material in lithium-ion batteries due to its low electrochemical potential, highest theoretical energy density and low density. There are, however, still significant challenges to be addressed such as Li-dendrite growth and low interfacial stability, which impede the practical application of Li metal anodes. In order to circumvent these shortcomings, herein, we present a gel polymer electrolyte containing imidazolium ionic liquid end groups with a perfluorinated alkyl chain (F-IL) to achieve both high ionic conductivity and Li ion transference number by fundamentally altering the solubility of salt within the gel electrolyte through Lewis-acidic segments in the polymer backbone. Moreover, the presence of F-IL moieties decreased the binding affinity of Li cation towards the glycol chains, enabling a rapid transfer of Li cation within the gel network. These structural features enabled the immobilization of anions on the ionic liquid segments to alleviate the space-charge effect while promoting stronger anion coordination and weaker cation coordination in the Lewis-acidic polymers. Accordingly, we realized a high Li ion conductivity (9.16×10-3 S cm-1 ) and high Li ion transference number of 0.69 simultaneously, along with a good electrochemical stability up to 4.55 V, while effectively suppressing Li dendrite growth. Moreover, the gel polymer electrolyte exhibited stable cycling performance of the Li|Li symmetric cell of 9 mAh cm-2 for more than 1800 hours and retained 86.7 % of the original capacity after 250 cycles for lithium-sulfur (Li-S) full cell.

| S-EPMC8518060 | biostudies-literature